Thermodynamics and kinetics of hydriding and dehydriding reactions in Mg-based hydrogen storage materials

被引：5

作者：

Qian Li ^{[1
,2
]}

Yangfan Lu ^{[1
]}

Qun Luo ^{[3
]}

Xiaohua Yang ^{[4
,5
]}

Yan Yang ^{[1
]}

Jun Tan ^{[1
]}

Zhihua Dong ^{[1
]}

Jie Dang ^{[1
]}

Jianbo Li ^{[1
]}

Yuan Chen ^{[1
]}

Bin Jiang ^{[1
]}

Shuhui Sun ^{[5
]}

Fusheng Pan ^{[1
]}

机构：

[1] National Engineering Research Center for Magnesium Alloys, College of Materials Science and Engineering, Chongqing University

[2] State Key Laboratory of Mechanical Transmissions, Chongqing University

[3] Institute of Quantum and Sustainable Technology (IQST), School of Chemistry and Chemical Engineering, Jiangsu University

[4] Institut National de la Recherche Scientifique-énergie Matériaux et Télécommunications

[5] State Key Laboratory of Advanced Special Steels, Shanghai Key Laboratory of Advanced Ferrometallurgy, School of Materials Science and Engineering,Shanghai University

来源：

Journal of Magnesium and Alloys | 2021年 / 06期

基金：

中国国家自然科学基金;

关键词：

D O I：

暂无

中图分类号：

TG139.7 [];

学科分类号：

080502 ;

摘要：

Mg-based materials are one of the most promising hydrogen storage candidates due to their high hydrogen storage capacity,environmental benignity,and high Clarke number characteristics.However,the limited thermodynamics and kinetic properties pose major challenges for their engineering applications.Herein,we review the recent progress in improving their thermodynamics and kinetics,with an emphasis on the models and the influence of various parameters in the calculated models.Subsequently,the impact of alloying,composite,and nanocrystallization on both thermodynamics and dynamics are discussed in detail.In particular,the correlation between various modification strategies and the hydrogen capacity,dehydrogenation enthalpy and temperature,hydriding/dehydriding rates are summarized.In addition,the mechanism of hydrogen storage processes of Mg-based materials is discussed from the aspect of classical kinetic theories and microscope hydrogen transferring behavior.This review concludes with an outlook on the remaining challenge issues and prospects.

引用

页码：1922 / 1941

页数：20

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