Study on the thermal decomposition kinetics of cis/trans-[Cu（gly）2]·H2O

被引：0
|
作者：
ZHANG Fengxing
机构：
来源：
Science China Chemistry | 2005年 / S1期
关键词：
copper(Ⅱ) complex; thermal analysis; thermal decomposition kinetics; cis/trans isomers; glycin;
D O I：
暂无
中图分类号：
O621.25 [];
学科分类号：
070303 ; 081704 ;
摘要：
The thermal decomposition reactions of the complexes cis/trans-[Cu(gly)2]·H2O were studied by TG-DSC methods. The results showed that they have similar decomposition process, which occur in two steps. The first step is the loss of water and the second step is the decomposition of anhydrous complexes. But for cis-[Cu(gly)2]·H2O, the temperature of losing water is higher than that of trans-isomer. Their reaction mechanisms of the two-step decomposition were also proposed.
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页码：70 / 73
页数：4
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