The Isomeric Structures of H2GeLiF, the Prototype Germylenoid

被引：0
|
作者：
Hua Yu QIU
Wan Yong MA
Guan Bin LI
Cong Hao DENG (Department of Chemical Engineering. Shandong Institute of Light Industry. Jinan 250100
Institute of Theoretical Chemistry. Shandong University
机构：
来源：
ChineseChemicalLetters | 1999年 / 06期
关键词：
Germylenoid; p-complex; ab initio;
D O I：
暂无
中图分类号：
O614 [金属元素及其化合物];
学科分类号：
070301 ; 081704 ;
摘要：
The structures of four isomeric forms of the model germylenoid, H2GeLiF. have been examined by ah initio MO theory. The most stable structure is suggested to be the p-complex 1.The other three species. three-membered ring 2, δ-complex 3 and tetrahedron 4. are also local minima on the potential energy surface. but are higher in energy.
引用
收藏
页码：511 / 514
页数：4
相关论文
共 50 条
  • [41] Theoretical prediction on the addition reaction of germylenoid H2GeFMgF with ethylene
    Zhang, Ming-Xia
    Yan, Bing-Fei
    Li, Wen-Zuo
    Li, Qing-Zhong
    Cheng, Jian-Bo
    JOURNAL OF THEORETICAL & COMPUTATIONAL CHEMISTRY, 2016, 15 (03):
  • [42] Theoretical investigation on the addition reaction of the germylenoid H2GeLiCl with acetone
    Zhango, Xiaolin
    Yan, Bingfei
    Li, Wenzuo
    TURKISH JOURNAL OF CHEMISTRY, 2021, 45 (04) : 1125 - +
  • [43] STRUCTURES OF 2 ISOMERIC INTERMEDIATES TO NOGARAMYCIN
    HIRAYAMA, N
    SHIRAHATA, K
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1989, 45 : 151 - 154
  • [44] The addition reactions of germylenoid H2GeAlCl3 with ethylene: a theoretical investigation
    Zhang, Mingxia
    Li, Wenzuo
    Li, Qingzhong
    Cheng, Jianbo
    JOURNAL OF MOLECULAR MODELING, 2017, 23 (07)
  • [45] The addition reactions of germylenoid H2GeAlCl3 with ethylene: a theoretical investigation
    Mingxia Zhang
    Wenzuo Li
    Qingzhong Li
    Jianbo Cheng
    Journal of Molecular Modeling, 2017, 23
  • [46] DFT study on the unsaturated germylenoid H2C=GeLiC1
    Li Wen-Zuo
    Tan Hai-Na
    Xiao Cui-Ping
    Gong Bao-An
    Cheng Jian-Bo
    ACTA PHYSICO-CHIMICA SINICA, 2007, 23 (11) : 1811 - 1814
  • [47] A DETERMINATION OF THE STRUCTURES OF THE ISOMERIC 2-CHLOROVINYLDICHLOROARSINES
    MCDOWELL, CA
    EMBLEM, HG
    MOELWYNHUGHES, EA
    JOURNAL OF THE CHEMICAL SOCIETY, 1948, (AUG): : 1206 - 1208
  • [48] THE ISOMERIC STRUCTURES OF SIH2LIF
    CLARK, T
    SCHLEYER, PV
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1980, 191 (02) : 347 - 353
  • [49] CRYSTAL-STRUCTURES OF 2 ISOMERIC CYCLOTRISILANES
    DEWAN, JC
    MURAKAMI, S
    SNOW, JT
    COLLINS, S
    MASAMUNE, S
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (13) : 892 - 894
  • [50] The insertion and H2 elimination reactions of H2GeFMgF germylenoid with RH (R = Cl, SH, PH2)
    Zhang, Ming-Xia
    Yan, Bing-Fei
    Li, Wen-Zuo
    Li, Qing-Zhong
    Cheng, Jian-Bo
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2017, 91 (09) : 1660 - 1668
12345