Nanocomposite Films of V2O5-MoO3 Xerogel with Poly Ethylene Oxide Intercalation

被引:0
|
作者
郑锦霞 [1 ]
机构
[1] Wuhan University of Technology
关键词
V 0.9Mo 0.1) 2O 5; PEO; intercalation; nanocomposite;
D O I
暂无
中图分类号
TB383 [特种结构材料];
学科分类号
070205 ; 080501 ; 1406 ;
摘要
Poly ethylene oxide(PEO) x-V 2O 5-MoO 3(x=0,0.5,1) films were prepared by the sol-gel method.The synthesis and structure of the films were investigated by XRD,TG-DTA,FTIR,etc.The results show that V 2O 5-MoO 3 xerogel has a layered structure and its interlayer space increased from 1.3181nm at x=0 to 1.7898nm at x=1 after the nanocomposite films were dried,and PEO in the interlayer changes the interface structure by forming hydrogen bonds with V=O bands.CV measurement indicates that the intercalation of PEO improves insertion/extration properties of Li+ ions in the interlayer.
引用
收藏
页码:35 / 37
页数:3
相关论文
共 50 条
  • [1] Nanocomposite films of V2O5-MoO3 xerogel with poly ethylene oxide intercalation
    Zheng, JX
    Chen, W
    Jiang, CS
    Xu, Q
    Ke, MZ
    JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY-MATERIALS SCIENCE EDITION, 2003, 18 (02): : 35 - 37
  • [2] Nanocomposite films of V2O5−MoO3 xerogel with poly ethylene oxide intercalation
    Zheng Jin-xia
    Chen Wen
    Jiang Cong-sheng
    Xu Qing
    KE Man-zhu
    Journal of Wuhan University of Technology-Mater. Sci. Ed., 2003, 18 (2): : 35 - 38
  • [3] Nanocomposite films of MoO3 xerogel with poly (ethylene oxide) (PEO) intercalation
    Hu, YS
    Chen, W
    Xu, Q
    Yuan, RZ
    JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY, 2001, 17 : S124 - S126
  • [4] INTERCALATION OF POLY(ETHYLENE OXIDE) IN V2O5 XEROGEL
    LIU, YJ
    DEGROOT, DC
    SCHINDLER, JL
    KANNEWURF, CR
    KANATZIDIS, MG
    CHEMISTRY OF MATERIALS, 1991, 3 (06) : 992 - 994
  • [5] Lithium insertion in poly(ethylene oxide)/MoO3 xerogel nanocomposite films
    Hu, YS
    Chen, W
    Xu, Q
    Yuan, RZ
    JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY-MATERIALS SCIENCE EDITION, 2002, 17 (04): : 29 - 31
  • [6] Lithium insertion in poly(ethylene oxide)/MoO3 xerogel nanocomposite films
    Hu Yong-sheng
    Chen Wen
    Xu Qing
    Yuan Run-zhang
    Journal of Wuhan University of Technology-Mater. Sci. Ed., 2002, 17 (4): : 29 - 31
  • [8] V2O5-MOO3 SYSTEM
    VOLKOV, VL
    TYNKACHE.GS
    TKACHENK.EV
    FOTIEV, AA
    ZHURNAL NEORGANICHESKOI KHIMII, 1972, 17 (10): : 2803 - &
  • [9] Electrochromic properties of poly(ethylene oxide)/V2O5 nanocomposite films
    Chen, W
    Xu, Q
    Hu, YS
    IONIC AND MIXED CONDUCTING CERAMICS IV, 2002, 2001 (28): : 384 - 390
  • [10] Electrical and electrochemical characterization of poly (ethylene oxide)/V2O5 xerogel electrochromic films
    Jin, Aiping
    Chen, Wen
    Zhu, Quanyao
    Yang, Ying
    Volkov, Victor L.
    Zakharova, Galina S.
    SOLID STATE IONICS, 2008, 179 (21-26) : 1256 - 1262