Solvent effects on hydrogen bonding between primary alcohols and esters

被引：0
|
作者：
DHARMALINGAM K.
RAMACHANDRAN K.
SIVAGURUNATHAN P.
机构：
[1] Department of Physics Annamalai University Annamalai Nagar 608002 Tamilnadu India
[2] Department of Physics Annamalai University Annamalai Nagar 608002 Tamilnadu India
来源：
Journal of Zhejiang University-Science A(Applied Physics & Engineering) | 2006年 / 11期
关键词：
FTIR spectroscopy; Primary alcohols; Esters; Hydrogen bonding; Solvent effect;
D O I：
暂无
中图分类号：
X703 [废水的处理与利用];
学科分类号：
083002 ;
摘要：
The interaction by hydrogen bond formation of some primary alcohols (1-heptanol, 1-octanol and 1-decanol) with esters (methyl methacrylate, ethyl methacrylate and butyl methacrylate) was investigated in non-polar solvents viz., n-heptane, CCl4 and benzene by means of FTIR spectroscopy. Formation constants and free energy changes of complex formation were determined. The dependence of the equilibrium constants and free energy changes of complex formation on the alkyl chain length of both the alcohols and esters are discussed. The solvent effect on the hydrogen bond formation is discussed in terms of specific interaction between the solute and solvent.
引用
收藏
页码：1928 / 1931
页数：4
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