Two novel meroterpenoids with a 6/10/5 tricyclic system containing a pyran-4-one ring from Arnebia euchroma

被引：0
|
作者：
Qin, Guoqing [1 ,2 ]
Guo, Pengju [1 ,3 ]
Wang, Qing [1 ,4 ]
Nikolovski, Gjorgi [1 ,2 ]
Wang, Wenqiong [1 ]
Xuan, Lijiang [1 ,2 ]
机构：
[1] Chinese Acad Sci, Shanghai Inst Mat Med, State Key Lab Drug Res, 501 Haike Rd, Shanghai 201203, Peoples R China
[2] Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China
[3] Fudan Univ, Sch Pharm, Shanghai 201203, Peoples R China
[4] Nanjing Univ Chinese Med, Sch Chinese Mat Med, Nanjing 210023, Peoples R China
来源：
TETRAHEDRON LETTERS | 2024年 / 151卷
基金：
中国国家自然科学基金;
关键词：
Arnebia euchroma; Meroterpenoids; Arnebic acids A -B; 6/10/5 tricyclic system; Pyran-4-one ring;
D O I：
10.1016/j.tetlet.2024.155318
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Two novel meroterpenoids, arnebic acid A (1) and B (2) with a new 6/10/5 tricyclic system containing a pyran-4-one ring, were isolated from the roots of Arnebia euchroma. Through extensive spectroscopic analysis, single-crystal X-ray crystallography analysis and ECD calculation, the structures with absolute configurations of 1 and 2 were unequivocally elucidated. Additionally, the plausible biosynthetic pathways for compounds 1 and 2 were deduced.
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页数：4
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