Optimization of CuAl2O4 Nanoparticles for Enhanced Photocatalytic Degradation of Organic Dyes Under UV and Visible Light

被引:0
|
作者
Abed, Sattar H. [1 ]
Reshak, Ali H. [1 ]
机构
[1] Univ Basrah, Coll Sci, Phys Dept, Basrah, Iraq
关键词
CuAl2O4; NPs; Organic dye degradation; Methyl violet; Reactive oxygen species; WATER; OXIDE; PHOTODEGRADATION; GENERATION;
D O I
10.1007/s10895-024-04054-4
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
Organic dyes, due to their persistence and toxicity, represent a significant environmental challenge. This study focuses on the photocatalytic degradation of organic dyes using CuAl2O4 nanoparticles, synthesized through the co-precipitation method, under visible light irradiation. The synthesized nanoparticles were thoroughly characterized using Fourier Transform Infrared (FT-IR) spectroscopy, Raman spectroscopy, and X-ray Diffraction (XRD) to determine their chemical, structural, and crystalline properties. The optical properties of the nanoparticles, particularly their ability to absorb light, were also investigated, highlighting their importance in enhancing photocatalytic performance. Methyl Violet dye was selected as a model pollutant to assess the photocatalytic efficiency of these nanoparticles. The results showed that the CuAl2O4 nanoparticles degraded about 72.49% of Methyl Violet in 120 min under UV and visible light, with the high efficiency attributed to the generation of electron-hole pairs and reactive oxygen species, including superoxide anions and hydroxyl radicals. These active agents are critical in the degradation process. The findings demonstrate the potential of CuAl2O4 nanoparticles as nontoxic and highly effective photocatalysts for environmental remediation, offering a promising solution for treating wastewater contaminated with hazardous organic dyes. This study enhances the understanding of the photocatalytic behavior of CuAl2O4 nanoparticles and emphasizes their potential in reducing environmental pollution through efficient degradation of harmful compounds.
引用
收藏
页数:16
相关论文
共 50 条
  • [31] Surface plasmon resonance enhanced photocatalytic activity of novel Au@CuAl2O4 fibers under visible light
    Qing Lin
    Shuyi Xia
    Zhengqiang Shi
    Bingxin Hua
    Yanhong Lin
    Huanbin Zhang
    Dong Liang
    Zhao Wang
    Xiaojuan Zhang
    Journal of Materials Science: Materials in Electronics, 2024, 35
  • [32] Surface plasmon resonance enhanced photocatalytic activity of novel Au@CuAl2O4 fibers under visible light
    Lin, Qing
    Xia, Shuyi
    Shi, Zhengqiang
    Hua, Bingxin
    Lin, Yanhong
    Zhang, Huanbin
    Liang, Dong
    Wang, Zhao
    Zhang, Xiaojuan
    JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2024, 35 (02)
  • [33] Synthesis and characterization of CdS/CuAl2O4 core-shell: application to photocatalytic eosin degradation
    Bellal, B.
    Trari, M.
    Afalfiz, A.
    APPLIED NANOSCIENCE, 2015, 5 (06) : 673 - 680
  • [34] Fabrication of highly visible-light-responsive ZnFe2O4/TiO2 heterostructures for the enhanced photocatalytic degradation of organic dyes
    Thanh Binh Nguyen
    Doong, Ruey-an
    RSC ADVANCES, 2016, 6 (105): : 103428 - 103437
  • [35] Photocatalytic degradation of organic dyes with hierarchical Bi2O2CO3 microstructures under visible-light
    Madhusudan, Puttaswamy
    Zhang, Jun
    Cheng, Bei
    Liu, Gang
    CRYSTENGCOMM, 2013, 15 (02): : 231 - 240
  • [36] Cu2O/MoS2 composites: a novel photocatalyst for photocatalytic degradation of organic dyes under visible light
    Xuexin Zhang
    Mingzhu Xia
    Fengyun Wang
    Wu Lei
    Ionics, 2020, 26 : 6359 - 6369
  • [37] Cu2O/MoS2 composites: a novel photocatalyst for photocatalytic degradation of organic dyes under visible light
    Zhang, Xuexin
    Xia, Mingzhu
    Wang, Fengyun
    Lei, Wu
    IONICS, 2020, 26 (12) : 6359 - 6369
  • [38] Enhanced photocatalytic degradation of Bisphenol A under visible light by Cr-TiO2 nanoparticles
    Mantilla, Angeles
    Benitez, Enrique Samaniego
    Valenzuela, Isaac Montes
    Ortiz, Guadalupe Romero
    Diaz, Sandra Cipagauta
    Rojas, Luis Lartundo
    Morales, Francisco Javier Tzompantzi
    Magana, Michelle Navarrete
    JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2025, 459
  • [39] Synthesis and characterization of CuAl2O4 nanoparticles: Application for the removal of Eriochrome Black T under solar light irradiation
    Lahmar, H.
    Douafer, S.
    Laouici, R.
    Hamdi, M.
    Souici, A.
    Trari, M.
    Benamira, M.
    INORGANIC CHEMISTRY COMMUNICATIONS, 2024, 163
  • [40] Optical CuAl2O4 used as photocatalyst for IC dye degradation
    Dabhade, Ganesh
    Malpure, Ankita
    Borhade, Ashok
    Shewale, Yogita
    Kushare, Sachin
    Daware, Gaurav
    Rajesh, Yennam
    WATER PRACTICE AND TECHNOLOGY, 2024, 19 (05) : 2032 - 2044