Optimization of CuAl2O4 Nanoparticles for Enhanced Photocatalytic Degradation of Organic Dyes Under UV and Visible Light

被引:0
|
作者
Abed, Sattar H. [1 ]
Reshak, Ali H. [1 ]
机构
[1] Univ Basrah, Coll Sci, Phys Dept, Basrah, Iraq
关键词
CuAl2O4; NPs; Organic dye degradation; Methyl violet; Reactive oxygen species; WATER; OXIDE; PHOTODEGRADATION; GENERATION;
D O I
10.1007/s10895-024-04054-4
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
Organic dyes, due to their persistence and toxicity, represent a significant environmental challenge. This study focuses on the photocatalytic degradation of organic dyes using CuAl2O4 nanoparticles, synthesized through the co-precipitation method, under visible light irradiation. The synthesized nanoparticles were thoroughly characterized using Fourier Transform Infrared (FT-IR) spectroscopy, Raman spectroscopy, and X-ray Diffraction (XRD) to determine their chemical, structural, and crystalline properties. The optical properties of the nanoparticles, particularly their ability to absorb light, were also investigated, highlighting their importance in enhancing photocatalytic performance. Methyl Violet dye was selected as a model pollutant to assess the photocatalytic efficiency of these nanoparticles. The results showed that the CuAl2O4 nanoparticles degraded about 72.49% of Methyl Violet in 120 min under UV and visible light, with the high efficiency attributed to the generation of electron-hole pairs and reactive oxygen species, including superoxide anions and hydroxyl radicals. These active agents are critical in the degradation process. The findings demonstrate the potential of CuAl2O4 nanoparticles as nontoxic and highly effective photocatalysts for environmental remediation, offering a promising solution for treating wastewater contaminated with hazardous organic dyes. This study enhances the understanding of the photocatalytic behavior of CuAl2O4 nanoparticles and emphasizes their potential in reducing environmental pollution through efficient degradation of harmful compounds.
引用
收藏
页数:16
相关论文
共 50 条
  • [1] Enhanced photocatalytic performance of CuAl2O4 nanoparticles spinel for dye degradation under visible light
    Kaci, M. M.
    Nasrallah, N.
    Atmani, F.
    Kebir, M.
    Guernanou, R.
    Soukeur, A.
    Trari, M.
    RESEARCH ON CHEMICAL INTERMEDIATES, 2021, 47 (09) : 3785 - 3806
  • [2] Enhanced photocatalytic performance of CuAl2O4 nanoparticles spinel for dye degradation under visible light
    M. M. Kaci
    N. Nasrallah
    F. Atmani
    M. Kebir
    R. Guernanou
    A. Soukeur
    M. Trari
    Research on Chemical Intermediates, 2021, 47 : 3785 - 3806
  • [3] Photocatalytic degradation of organic dyes under UV-Visible light using capped ZnS nanoparticles
    Sharma, Manoj
    Jain, Tarun
    Singh, Sukhvir
    Pandey, O. P.
    SOLAR ENERGY, 2012, 86 (01) : 626 - 633
  • [4] Preparation of controllable morphology CuAl2O4 and influence on visible light photocatalytic properties
    Jiang, Yanyan
    Du, Xingke
    Zhang, Jiwen
    Hu, Zhiqiang
    Liu, Jingxiao
    Hao, Hongshun
    Kuei Suan Jen Hsueh Pao/Journal of the Chinese Ceramic Society, 2013, 41 (09): : 1296 - 1300
  • [5] Synthesis and visible-light photocatalytic property of spinel CuAl2O4 for vehicle emissions
    Zhuohong Cong
    Liang Zhou
    Nanxiang Zheng
    Taiwo Sesay
    Environmental Science and Pollution Research, 2023, 30 : 64123 - 64136
  • [6] Synthesis and photocatalytic investigation of ZnFe2O4 in the degradation of organic dyes under visible light
    Oliveira, Thayane Portela
    Marques, Gleison Neres
    Macedo Castro, Mario Andrean
    Viana Costa, Rayssa Cristina
    Rangel, Jose Hilton Gomes
    Rodrigues, Samuel Filgueiras
    dos Santos, Clenilton Costa
    Oliveira, Marcelo Moizinho
    JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T, 2020, 9 (06): : 15001 - 15015
  • [7] Synthesis and visible-light photocatalytic property of spinel CuAl2O4 for vehicle emissions
    Cong, Zhuohong
    Zhou, Liang
    Zheng, Nanxiang
    Sesay, Taiwo
    ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH, 2023, 30 (23) : 64123 - 64136
  • [8] Effect of Chelating Agent on Morphology and Visible-light Photocatalytic Performance of CuAl2O4 Powders
    Jiang Yanyan
    Sui Xiaotao
    Ning Guiling
    Chen Min
    Wang Chengyu
    RARE METAL MATERIALS AND ENGINEERING, 2010, 39 : 438 - 441
  • [9] Illuminating the Power of V2O5 Nanoparticles: Efficient Photocatalytic Degradation of Organic Dyes under Visible Light
    Abed, Sattar H.
    Reshak, Ali H.
    JOURNAL OF FLUORESCENCE, 2024,
  • [10] Imidazolium ionic liquid functionalized nano dendritic CuAl2O4 for visible light-driven photocatalytic degradation of dye pollutant
    Feng, Haidong
    He, Chunlin
    Ma, Guofeng
    Zhiani, Rahele
    INORGANIC CHEMISTRY COMMUNICATIONS, 2021, 132