Catalytic Atroposelective Electrophilic Amination to Access Axially Chiral Diaryl Phenols

被引：0

作者：

Shao, Ying ^{[1
]}

Wang, Han ^{[1
]}

Chen, Qiang ^{[1
]}

Tang, Shengbiao ^{[1
]}

Sun, Jiangtao ^{[1
]}

机构：

[1] Changzhou Univ, Sch Petrochem Engn, Jiangsu Key Lab Adv Catalyt Mat & Technol, Changzhou 213164, Peoples R China

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2025年

基金：

中国国家自然科学基金;

关键词：

Atroposelective; Axial chirality; Diaryl phenols; Sulfonamides; SULFENYLATION; HYBRIDIZATION; CONSTRUCTION; ANTIOXIDANT; ANILINES;

D O I：

10.1002/asia.202500239

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An enantioselective synthesis of axially chiral diaryl phenols containing sulfonamide groups has been achieved involving an electrophilic amination of 1,1'-biaryl-2,6-diols with N-sulfonyl quinone diimines, catalyzed by a chiral phosphoric acid. This atroposelective reaction offers a modular approach to enantiopure diaryl phenols, with good-to-excellent yields.

引用

页数：6

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