Palladium-Catalyzed Selective B(3)-Esterification of o-Carboranes with CO and Alcohols

被引：0

作者：

Zhu, Shuai ^{[1
]}

Liu, Yizhen ^{[1
]}

Xie, Zuowei ^{[1
]}

机构：

[1] Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Dept Chem, Shenzhen 518055, Guangdong, Peoples R China

来源：

ORGANIC LETTERS | 2025年 / 27卷 / 10期

基金：

中国国家自然科学基金;

关键词：

BORON CLUSTERS; H BONDS; CHEMISTRY; CARBONYLATION;

D O I：

10.1021/acs.orglett.5c00308

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Selective functionalization of o-carboranes has received tremendous attention, specifically in the regioselective modification of the ten chemically similar BH vertices within o-carborane cage. We disclose herein a strategy for palladium-catalyzed esterification of the B(3)-H bond in o-carboranes using tungsten hexacarbonyl as a carbon monoxide source. The corresponding functionalized o-carboranes were prepared in moderate to very good yields with excellent regioselectivity.

引用

页码：2429 / 2432

页数：4

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