Cu(OTf)2-catalyzed multicomponent reactions

被引:0
|
作者
Colombo, Sara [1 ]
Loro, Camilla [1 ]
Beccalli, Egle M. [2 ]
Broggini, Gianluigi [1 ]
Papis, Marta [1 ]
机构
[1] Univ Insubria, Dipartimento Sci & Alta Tecnol, Via Valleggio 9, I-22100 Como, Italy
[2] Univ Milan, Sez Chim Gen & Organ A Marchesini, DISFARM, Via Venezian 21, I-20133 Milan, Italy
来源
关键词
cascade process; copper catalysis; heteropolycycles; multicomponent reactions; one-pot reaction; ONE-POT SYNTHESIS; HIGHLY EFFICIENT SYNTHESIS; HIGH-YIELD SYNTHESIS; COPPER(II) TRIFLATE; CU(OTF)(2); ALDEHYDES; CATALYST; CYCLOADDITION; DERIVATIVES; ALKYNES;
D O I
10.3762/bjoc.21.7
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
This review reports the achievements in copper(II) triflate-catalyzed processes concerning the multicomponent reactions, applied to the synthesis of acyclic and cyclic compounds. In particular, for the heteropolycyclic systems mechanistic insights were outlined as well as cycloaddition and aza-Diels-Alder reactions were included. These strategies have gained attention due to their highly atomand step-economy, one-step multi-bond forming, mild reaction conditions, low cost and easy handling.
引用
收藏
页码:122 / 145
页数:24
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