CeCl3-Catalyzed C-H Alkylation of N-Sulfonyl Ketimines with Alkanes and Ether via Photoinduced Ligand-to-Metal Charge Transfer

被引：0

作者：

Zhou, Bin ^{[1
]}

Dong, Min ^{[4
]}

Wang, Wei ^{[4
]}

Yu, Sha ^{[4
]}

Yue, Huilan ^{[2
,3
]}

Wei, Wei ^{[2
,3
]}

Yi, Dong ^{[4
]}

机构：

[1] Shaoyang Univ, Coll Pharm, Shaoyang 422099, Peoples R China

[2] Northwest Inst Plateau Biol, Qinghai Prov Key Lab Tibetan Med Res, Xining 810008, Qinghai, Peoples R China

[3] Northwest Inst Plateau Biol, CAS Key Lab Tibetan Med Res, Xining 810008, Qinghai, Peoples R China

[4] Southwest Med Univ, Sch Pharm, Green Pharmaceut Technol Key Lab Luzhou City, Luzhou 646000, Sichuan, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2024年 / 89卷 / 24期

基金：

中国国家自然科学基金;

关键词：

CYCLIC ALDIMINES; FUNCTIONALIZATION; ALKENES;

D O I：

10.1021/acs.joc.4c02205

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A cerium-catalyzed C-H alkylation of N-sulfonyl ketimines with low-cost and readily available alkanes as alkyl sources was developed. This transformation proceeded through the synergy of photoinitiated ligand-to-metal charge transfer (LMCT) using a chlorine radical as an HAT reagent and air as a green oxidant. A series of alkylated N-sulfonyl ketimines were synthesized with moderate to good yields in a highly atom-economic manner under chemical oxidant-free conditions.

引用

页码：18337 / 18343

页数：7

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