Nickel-Catalyzed Transannulation Reaction of 1,2,3,4-Benzothiatriazin-1,1(2H)-dioxide with Alkyne and the Detailed Investigation of Reaction Mechanism

被引：0
|
作者：
Thorat, Vijaykumar H. [1 ]
Chuang, Ya-Chu [1 ]
Hsieh, Chung-Hung [1 ]
Hsieh, Jen-Chieh [1 ]
机构：
[1] Tamkang Univ, Dept Chem, New Taipei City 251301, Taiwan
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2025年
关键词：
Nickel Catalysis; Denitrogenative Reaction; Transannulation; Cycloaddition reaction; Sultam; SULTAMS; COMPLEXES; DESIGN;
D O I：
10.1002/adsc.202500231
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Herein, we provide two nickel complexes and a series of control experiments to study the mechanism of the nickel-catalyzed transannulation reaction of 1,2,3,4-benzo-thiatriazin-1,1(2H)-dioxide with aryne and alkyne in detail. In addition, we provide a new protocol for the cycloaddition of 1,2,3,4-benzothiatriazin-1,1(2H)-dioxide with alkyne on the basis of a similar reaction pathway.
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页数：8
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