Nickel-Catalyzed Transannulation Reaction of 1,2,3,4-Benzothiatriazin-1,1(2H)-dioxide with Alkyne and the Detailed Investigation of Reaction Mechanism

被引：0

作者：

Thorat, Vijaykumar H. ^{[1
]}

Chuang, Ya-Chu ^{[1
]}

Hsieh, Chung-Hung ^{[1
]}

Hsieh, Jen-Chieh ^{[1
]}

机构：

[1] Tamkang Univ, Dept Chem, New Taipei City 251301, Taiwan

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2025年

关键词：

Nickel Catalysis; Denitrogenative Reaction; Transannulation; Cycloaddition reaction; Sultam; SULTAMS; COMPLEXES; DESIGN;

D O I：

10.1002/adsc.202500231

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Herein, we provide two nickel complexes and a series of control experiments to study the mechanism of the nickel-catalyzed transannulation reaction of 1,2,3,4-benzo-thiatriazin-1,1(2H)-dioxide with aryne and alkyne in detail. In addition, we provide a new protocol for the cycloaddition of 1,2,3,4-benzothiatriazin-1,1(2H)-dioxide with alkyne on the basis of a similar reaction pathway.

引用

页数：8

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