Realization of an Elusive U(III) Imido Complex

被引：1

作者：

Reinhart, Erik D. ^{[1
]}

Studvick, Chad M. ^{[2
]}

Billow, Brennan S. ^{[3
]}

Odom, Aaron L. ^{[4
]}

Popov, Ivan A. ^{[5
]}

Boncella, James M. ^{[1
,5
]}

机构：

[1] Pacific Northwest Natl Lab, Richland, WA 99345 USA

[2] Univ Akron, Dept Chem, Akron, OH 44325 USA

[3] Los Alamos Natl Lab, Los Alamos, NM 87545 USA

[4] Michigan State Univ, Dept Chem, 578 S Shaw Lane, E Lansing, MI 48824 USA

[5] Washington State Univ, Dept Chem, Pullman, WA 99164 USA

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2025年 / 31卷 / 09期

基金：

美国国家科学基金会;

关键词：

Low-valent uranium; Reduction; Imidos; Arene complexes; Electronic structure; VALENT ORGANOURANIUM COMPLEXES; C-H BOND; ELECTRONIC-STRUCTURE; TRIVALENT URANIUM; ARENE COMPLEX; IONIC-SOLUTIONS; REACTIVITY; LIGAND; CHEMISTRY; ACTIVATION;

D O I：

10.1002/chem.202403859

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reduction of Cp*(TrippTerN)UI with KC8 generates (KCp*(TrippTerN)UI)2, the first example of a trivalent uranium imido, a previously elusive species, which are commonly unstable. Experimental and computational results indicate that the K+ coordination is responsible for this isolable U(III) monoimido complex.

引用

页数：6

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