Dinuclear iridium complexes ligated by lithium-ion endohedral fullerene Li+@C60

被引：0
|
作者：
Fukushi, Chinari [1 ]
Komuro, Takashi [1 ]
Hashimoto, Hisako [1 ]
机构：
[1] Tohoku Univ, Grad Sch Sci, Dept Chem, Sendai 9808578, Japan
来源：
CHEMICAL COMMUNICATIONS | 2025年 / 61卷 / 11期
基金：
日本学术振兴会;
关键词：
TRANSITION-METAL-COMPLEXES; LI-AT-C-60; MOLECULES; CHEMISTRY; C-60;
D O I：
10.1039/d4cc05485g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The diiridium complexes of lithium-ion endohedral fullerene Li+@C60 were synthesised in high yields. X-ray crystallography revealed the eta 2:eta 2-coordination of Li+@C60 and the disorder of the Li+ ion over two sites close to the coordinated carbons. 13C NMR study suggested the presence of dynamic behaviour via haptotropic rearrangements. UV/Vis and CV characteristics were also investigated experimentally and theoretically.
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页数：5
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