Research Progress in the Synthesis of CL-20 and the Application of Catalysts in the Synthesis

被引:0
|
作者
Wang, Hui [1 ]
Cheng, Yitong [2 ]
Macheka, Henrie George [1 ]
An, Huiyong [2 ]
Xie, Yuan [2 ]
机构
[1] Liaoning Petrochem Univ, Sch Civil Engn, Fushun, Liaoning, Peoples R China
[2] Liaoning Petrochem Univ, Sch Environm & Safety Engn, Fushun, Liaoning, Peoples R China
关键词
CL-20; synthetic process; hydrodebenzylation; nitration; catalyst; OPTIMIZATION; POLYAZAPOLYCYCLICS; CONDENSATION; ALDEHYDES; EFFICIENT; NITRATION; GLYOXAL; AMINES; GREEN;
D O I
10.1002/prep.202400088
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
As the highest energy and most powerful elemental energetic compound known so far, CL-20 has attracted much attention since its advent. With its use not solely being the production of explosives, but also has great application prospects in other fields, such as propellants and smoke agents. In this paper, the synthetic process of CL-20 is reviewed. It is divided into two parts: the traditional synthetic method and the new synthetic method. Especially due to the improvement of traditional synthetic method. In recent years, most studies on CL-20 focus on how to use catalysts to optimize the two processes of hydrodebenzylation of HBIW and the nitration synthesis of CL-20 with different nitration precursors. Therefore, this review focuses on the utilization of catalysts in the synthetic process, and predicts a bright future research direction focused on CL-20. image
引用
收藏
页数:12
相关论文
共 50 条
  • [41] Research progress on cu-based catalysts for alcohol synthesis
    Liu, Kefeng
    Liu, Xiaotong
    Li, Qingxun
    Xiao, Haicheng
    Kong, Fanhua
    Shiyou Xuebao, Shiyou Jiagong/Acta Petrolei Sinica (Petroleum Processing Section), 2015, 31 (03): : 821 - 830
  • [42] Research Progress on Bifunctional Catalysts for the Synthesis of Gasoline from Syngas
    Song Yu
    Wu Chongchong
    Wang Wenbo
    Xin Jing
    Zhang Haihong
    Wang Lianying
    Zhang Peipei
    Li Hongbao
    China Petroleum Processing & Petrochemical Technology, 2024, 26 (04) : 152 - 169
  • [43] Research progress of catalysts for synthesis of low-carbon alcohols from synthesis gas
    Xue, Xiaoxiao
    Weng, Yujing
    Yang, Shicheng
    Meng, Shihang
    Sun, Qi
    Zhang, Yulong
    RSC ADVANCES, 2021, 11 (11) : 6163 - 6172
  • [44] Progress in synthesis of homogeneous chromium catalysts and their application in olefin polymerization
    Zhang, H
    Huang, JL
    Qian, YL
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2002, 22 (12) : 981 - 989
  • [45] Research on the thermal decomposition behavior of NEPE propellant containing CL-20
    Ding, Li
    Zhao, Feng-Qi
    Pan, Qing
    Xu, Hui-Xiang
    JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2016, 121 : 121 - 127
  • [46] DFT studies on the four polymorphs of crystalline CL-20 and the influences of hydrostatic pressure on ε-CL-20 crystal
    Xu, Xiao-Juan
    Zhu, Wei-Hua
    Xiao, He-Ming
    JOURNAL OF PHYSICAL CHEMISTRY B, 2007, 111 (08): : 2090 - 2097
  • [47] Preparation of Cellulose/CL-20 Composite Energetic Aerogels by Crystal Growth of CL-20 in Cellulose Solution
    Bian, Hongli
    Shao, Ziqiang
    Liu, Jianxin
    Chen, Ken
    Zhang, Xuan
    CRYSTAL GROWTH & DESIGN, 2020, 20 (10) : 6811 - 6819
  • [48] Research on vibrational features of CL-20/MTNP cocrystal by terahertz spectroscopy
    Liu Quan-Cheng
    Yang Fu
    Zhang Qi
    Duan Yong-Wei
    Deng Hu
    Shang Li-Ping
    ACTA PHYSICA SINICA, 2024, 73 (19)
  • [49] Hexanitrohexaazaisowurtzitane (CL-20) and CL-20-based formulations (review)
    U. R. Nair
    R. Sivabalan
    G. M. Gore
    M. Geetha
    S. N. Asthana
    H. Singh
    Combustion, Explosion and Shock Waves, 2005, 41 : 121 - 132
  • [50] Research on the Mechanism and Kinetics of Polymorphic Transitions of ε-CL-20 in Composite Systems
    Guo, Xue-yong
    Zhang, Pu
    Xu, Jin-jiang
    Wang, Zheng-hong
    Jiao, Qing-jie
    CENTRAL EUROPEAN JOURNAL OF ENERGETIC MATERIALS, 2015, 12 (04): : 689 - 702