Is Light Necessary for the Formation of Phosgene from the Oxidation of Chloroform?

被引：0
|
作者：
Mousavi, Aliyar [1 ]
机构：
[1] Nashua Community Coll, Dept Biol & Hlth Sci, Nashua, NH 03063 USA
来源：
ACS CHEMICAL HEALTH & SAFETY | 2025年
关键词：
chloroform; light; oxidation; phosgene; spontaneity;
D O I：
10.1021/acs.chas.5c00014
中图分类号：
R1 [预防医学、卫生学];
学科分类号：
1004 ; 120402 ;
摘要：
The formation of phosgene from the oxidation of chloroform is a known chemical safety issue. However, some laboratory safety case reports make us question the exact role of light in the oxidation process. In this Letter, the necessity of light in chemical reactions was briefly examined and categorized as thermodynamic or kinetic, and it was concluded that the role of light in the formation of phosgene from the oxidation of chloroform is only kinetic.
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页数：3
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