Pb9O4(BO3)2(NO3)4: A Lead Borate-Nitrate Containing an Anion-Centered [O8Pb18]∞ Chain with Large Optical Anisotropy

被引：0
|
作者：
Han, Mingye [1 ]
Dou, Danyang [1 ]
Chen, Cheng [1 ]
Zhang, Bingbing [1 ,2 ]
Wang, Ying [1 ,2 ]
机构：
[1] Hebei Univ, Coll Chem & Mat Sci, Hebei Res Ctr Basic Discipline Synthet Chem, Minist Educ,Key Lab Med Chem Mol Diag,Key Lab Chem, Baoding 071002, Peoples R China
[2] Hebei Univ, Inst Life Sci & Green Dev, Baoding 071002, Peoples R China
来源：
INORGANIC CHEMISTRY | 2025年 / 64卷 / 04期
基金：
中国国家自然科学基金;
关键词：
CRYSTAL-CHEMISTRY; TETRAHEDRA; CARBONATES;
D O I：
10.1021/acs.inorgchem.4c05416
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
In the field of structural chemistry, crystals containing the [OM4] tetrahedra (M = metal cation) structure have been well documented. However, compounds containing both [OPb4] tetrahedra and pi-conjugated groups are less reported due to their structural complexity. In this work, a new lead borate-nitrate, Pb9O4(BO3)2(NO3)4, has been synthesized by a high temperature melt method. Notably, the structure of Pb9O4(BO3)2(NO3)4 contains special [O8Pb18]infinity chains formed by the [OPb4] tetrahedra. This compound possesses a large optical anisotropy with birefringence of Delta n = 0.117 at 546 nm.
引用
收藏
页码：1637 / 1641
页数：5
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