Visible-light-promoted azidation/arylation of unactivated alkenes with Togni-N3via electron donor-acceptor complexes

被引：0

作者：

Xie, Peng ^{[1
]}

Gao, Yue ^{[1
]}

Wu, Chenqi ^{[1
]}

Cheng, Peidong ^{[3
]}

Zhang, Yong ^{[2
]}

Sun, Song ^{[3
]}

机构：

[1] Suzhou Polytech Inst Agr, Fac Food Sci & Technol, Suzhou 215008, Peoples R China

[2] Suzhou Ind Pk Inst Serv & Outsourcing, Suzhou 215123, Jiangsu, Peoples R China

[3] Changzhou Univ, Adv Catalysis & Green Mfg Collaborat Innovat Ctr, Sch Petrochem Engn, Changzhou 213164, Peoples R China

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2025年 / 23卷 / 07期

关键词：

AZIDATION; STYRENES; ACIDS; ALDEHYDES; AZIDES;

D O I：

10.1039/d4ob01861c

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A visible-light-promoted azidation/arylation of unactivated alkenes with Togni-N3 has been achieved, leading to a series of azidated pyrrolo[1,2-a]indoles under photocatalyst-free conditions. Notably, an EDA complex derived from the electron-rich indole derivatives and Togni-N3 served as the key intermediate in this reaction.

引用

页码：1607 / 1611

页数：5

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