Visible-light-promoted azidation/arylation of unactivated alkenes with Togni-N3via electron donor-acceptor complexes

被引：0

作者：

Xie, Peng ^{[1
]}

Gao, Yue ^{[1
]}

Wu, Chenqi ^{[1
]}

Cheng, Peidong ^{[3
]}

Zhang, Yong ^{[2
]}

Sun, Song ^{[3
]}

机构：

[1] Suzhou Polytech Inst Agr, Fac Food Sci & Technol, Suzhou 215008, Peoples R China

[2] Suzhou Ind Pk Inst Serv & Outsourcing, Suzhou 215123, Jiangsu, Peoples R China

[3] Changzhou Univ, Adv Catalysis & Green Mfg Collaborat Innovat Ctr, Sch Petrochem Engn, Changzhou 213164, Peoples R China

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2025年 / 23卷 / 07期

关键词：

AZIDATION; STYRENES; ACIDS; ALDEHYDES; AZIDES;

D O I：

10.1039/d4ob01861c

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A visible-light-promoted azidation/arylation of unactivated alkenes with Togni-N3 has been achieved, leading to a series of azidated pyrrolo[1,2-a]indoles under photocatalyst-free conditions. Notably, an EDA complex derived from the electron-rich indole derivatives and Togni-N3 served as the key intermediate in this reaction.

引用

页码：1607 / 1611

页数：5

共 50 条

[1] Visible-Light-Promoted Hydroxydifluoroalkylation of Alkenes Enabled by Electron Donor-Acceptor Complex
Xie, Zhen-Zhen
Zheng, Yu
Tang, Kai
Guan, Jian-Ping
Yuan, Chu-Ping
Xiao, Jun-An
Xiang, Hao-Yue
Chen, Kai
Chen, Xiao-Qing
Yang, Hua
ORGANIC LETTERS, 2021, 23 (24) : 9474 - 9479
[2] Visible-light-promoted difluoroamidated oxindole synthesis via electron donor-acceptor complexes
Wang, Wei-Feng
Liu, Tao
Cheng, Yan-Liang
Song, Qin-Hua
ORGANIC & BIOMOLECULAR CHEMISTRY, 2024, 22 (04) : 805 - 810
[3] Visible-light-promoted thioetherification of aryl diazonium salts with thiols via electron donor-acceptor complexes
Jiang, Zhou
You, Ke
Wu, Haibo
Xu, Mengyu
Luo, Jin
Zhou, Yuan
Wang, Tao
MOLECULAR CATALYSIS, 2025, 572
[4] Visible-Light-Promoted C3-Sulfenylindoles with Arylsulfonyl Chlorides via Electron Donor-Acceptor Complex
Xue, Ziqian
Yang, Wenjing
Huang, Qiuzhan
Zhou, Cong-Ying
Guo, Zhen
JOURNAL OF ORGANIC CHEMISTRY, 2024, 89 (11): : 7591 - 7597
[5] Visible-light-promoted trifluoromethylation/arylation of unactivated alkenes with Togni-CF3 for the synthesis of trifluoromethylated pyrrolo [1,2-a]indoles
Qin, Hongni
Zhang, Yong
Sun, Song
TETRAHEDRON LETTERS, 2025, 157
[6] Visible light-driven fluoroalkylthiocyanation of alkenes via electron donor-acceptor complexes
Li, Zebiao
Wang, Shan
Huo, Yumei
Wang, Bing
Yan, Jun
Guo, Quanping
ORGANIC CHEMISTRY FRONTIERS, 2021, 8 (12) : 3076 - 3081
[7] Visible-Light-Promoted Cascade Radical Cyclization for Difluorochroman-4-Ones Via Electron Donor-Acceptor Complexes
Wang, Wei-Feng
Song, Qin-Hua
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2024, 27 (43)
[8] Visible-Light-Promoted Thiolation of Benzyl Chlorides with Thiosulfonates via a Photoactive Electron Donor-Acceptor Complex
Gong, Chao
Huang, Jialun
Cai, Liuyan
Yuan, Yilong
Pu, Tonglv
Huang, Mingjie
Wu, Si-Hai
Wang, Lianhui
JOURNAL OF ORGANIC CHEMISTRY, 2024, 89 (13): : 9450 - 9461
[9] Pyrroline Synthesis via Visible-Light-Promoted Hydroimination of Unactivated Alkenes with N,N′-Dimethylpropylene Urea as H-Donor
Cai, Sai-Hu
Wang, Ding-Xing
Ye, Lu
Liu, Ze-Yao
Feng, Chao
Loh, Teck-Peng
ADVANCED SYNTHESIS & CATALYSIS, 2018, 360 (06) : 1262 - 1266
[10] Visible-Light-Induced Radical Arylation Reactions via Electron Donor-Acceptor Complex
Yi Rongnana
He Weimin
CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2022, 42 (08) : 2590 - 2592

← 1 2 3 4 5 →