Alkali-Mediated/Catalyzed Transition-Metal-Free Tandem Reaction Triggered by the Borrowing Hydrogen and Aerobic Dehydrogenation Processes of Alcohols

被引：0
|
作者：
Chang, Ai [1 ]
Zhou, Weihao [1 ]
Zhao, Sicong [1 ]
Song, Haowen [1 ]
Zhuang, Yi [1 ]
Lin, Yamei [2 ,3 ]
Huang, Shenlin [2 ]
Lu, Guo-Ping [1 ]
机构：
[1] Nanjing Univ Sci & Technol, Sch Chem & Chem Engn, Nanjing 210094, Peoples R China
[2] Nanjing Forestry Univ, Int Innovat Ctr Forest Chem & Mat, Nanjing 210037, Peoples R China
[3] Nanjing Normal Univ, Sch Food Sci & Pharmaceut Engn, Wenyuanst 200, Nanjing 210032, Peoples R China
来源：
CHEMISTRYSELECT | 2024年 / 9卷 / 40期
关键词：
Aerobic dehydrogenation; Alcohol; Alkali catalysis; Borrowing hydrogen; Tandem reaction; DEHYDRATIVE N-ALKYLATION; ALPHA-ALKYLATION; CATALYST; AMINES; EFFICIENT; KETONES; OXIDATION; INDOLES; GREEN;
D O I：
10.1002/slct.202403630
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The transformation of alcohols to important classes of compounds is a central topic in chemistry because they are abundant, renewable, and attractive building blocks. The alkali-mediated/catalyzed borrowing hydrogen and aerobic dehydrogenation processes of alcohols open a new and sustainable access for the alcohol conversion under transition-metal-free conditions. In this review, we summarize the recent alkali-mediated/catalyzed sequential reactions involving the borrowing hydrogen and aerobic dehydrogenation processes of alcohols. Furthermore, this review not only introduces the tentative pathways of these transformations, but also discusses the role of alkali, solvent effects, and substrate reactivity on these reactions.
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页数：21
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