Novel Endpoint Characterization Factors for Life Cycle Impact Assessment of Terrestrial Acidification

Human activities involving combustion and agricultural practices, among others, lead to the release of acidifying compounds such as nitrogen oxides (NOx), sulfur oxides (SOx), and ammonia (NH3). These substances are the main drivers of human-induced terrestrial acidification, a geochemical process resulting mainly in the decline of soil pH, causing ecosystem damage and biodiversity loss. A relevant tool to quantify impacts of human activities is Life Cycle Assessment where characterization factors are used to estimate the potential environmental impacts per unit of emission. These are derived from models of environmental processes occurring along the stressor's impact pathway, connecting an emission to its potential environmental damage. Here, new ecosystem quality characterization factors for terrestrial acidification were developed, assessing the potential global loss of vascular plant species. The final values combine four elements: existing fate factors, updated soil response factors, recently revised effect factors, and the Global Extinction Probability. The latter allows to convert the local decline in species richness into a global species loss. The regionalized marginal characterization factors provided represent the aggregated global biodiversity impact in all the world's ecoregions due to an acidifying emission (of NOx, NHx, or SOx) from a specific country. The values cover five orders of magnitude (from 10- 16 to 10-11 PDFglobal.yr.kgemitted- 1 ), and the comparison to currently implemented values has helped both validate the calculation pathway and confirm the need for updated factors. Following current harmonization recommendations, terrestrial acidification impacts can now be compared to those from other stressors estimated in global Potential Disappeared Fraction of species.