Synthesis and Comprehensive Characterization of Amino Acid-Derived Vinyl Monomer Gels

被引：0
|
作者：
Beddok, Claire [1 ,2 ,3 ]
Zimmer, Alicia [1 ]
Blanchard, Carole Calas [2 ,3 ]
Fuks, Gad [1 ]
机构：
[1] Univ Perpignan, Ctr Rech Insulaires & Observ Environm, Labex CORAIL, UAR 3278,UPVD,CNRS,EPHE,PSL, Via Domitia, F-66860 Perpignan, France
[2] Univ Perpignan, Biocapteurs Anal Environm, Via Domitia, F-66860 Perpignan, France
[3] Sorbonne Univ, Lab Biodivers & Biotechnol Microbienne, CNRS, USR3579,Observ Oceanol, F-66650 Banyuls Sur Mer, France
来源：
ACS OMEGA | 2024年 / 9卷 / 45期
关键词：
POLYMERS;
D O I：
10.1021/acsomega.4c05246
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In this study, we report an easy synthetic pathway to vinyl monomers derivatized with amino acids. Tyrosine-, phenylalanine-, tryptophan-, leucine-, and methionine-based monomers were synthesized, and their polymerization in the presence of cross-linking agents led to the formation of amino acid-based gels. The nature of cross-linker, the time of polymerization, and the type of initiation (photopolymerization or thermopolymerization) were investigated. The obtained gels were characterized using a combination of thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), rheology, scanning electron microscopy (SEM), and solid-state nuclear magnetic resonance (NMR) spectroscopy. These novel amino acid-based gels could find applications in various areas such as drug delivery, biosensing, and biotechnology.
引用
收藏
页码：45053 / 45058
页数：6
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