First comb-like copolymer of poly(ethyl 2-cyanoacrylate) grafted as a side-chain to dextran

被引：0

作者：

Dyatlov, Valery A. ^{[1
]}

Seregina, Tatiana S. ^{[1
]}

Derevnin, Igor A. ^{[1
]}

Krivoborodov, Efrem G. ^{[1
]}

Belyaeva, Anna A. ^{[2
]}

Malashicheva, Anna B. ^{[2
]}

V. Dyatlov, Alexander ^{[3
]}

机构：

[1] DI Mendeleev Univ Chem Technol Russia, Moscow 125047, Russia

[2] Russian Acad Sci, Inst Cytol, St Petersburg 194064, Russia

[3] Hebrew Univ Jerusalem, IL-9112001 Jerusalem, Israel

来源：

MENDELEEV COMMUNICATIONS | 2024年 / 34卷 / 06期

关键词：

ethyl; 2-cyanoacrylate; dextran; polysaccharides; anionic polymerization; comb-like graft copolymer; MALDI-TOF mass spectrometry; NANOCAPSULES;

D O I：

10.1016/j.mencom.2024.10.035

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first comb-like cyanoacrylic copolymer was synthesized by anionic polymerization of ethyl 2-cyanoacrylate in an aqueous solution of dextran of M w = 50 +/- 5 kDa. The copolymer was explored by NMR and Fourier IR spectroscopy, as well asby MALDI-TOF mass-spectrometry methods.It contains up to 10 cyanoacrylate units grafted to anhydroglucose cycles of dextran main chain, multi- substituted glycose units were not detected.

引用

页码：881 / 883

页数：3

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