Synthesis and structure of pentakis(2-aminopyridinium) nonavanado(V)tellurate(VI)

被引：0

作者：

Mrad, Houda ^{[1
]}

Maalaoui, Ahlem ^{[1
]}

Rzaigui, Mohamed ^{[1
]}

Akriche, Samah ^{[1
]}

机构：

[1] Univ Carthage, Fac Sci Bizerte, Lab Mat Chem LR13ES08, Zarzouna 7021, Bizerte, Tunisia

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2024年 / 80卷

关键词：

crystal structure; Hirshfeld surface; polyoxometalate; nonavanado(V)tellurate(VI); 2-aminopyridine; non-covalent interactions;

D O I：

10.1107/S2056989024010533

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, (C5H7N2)(5)[TeV9O28], the tellurium and vanadium atoms are statistically disordered over two of the ten metal-atom sites in the [TeV9O28](5-) heteropolyanion. The anions stack along [100] and are extended into a three-dimensional supramolecular network through N-H center dot center dot center dot O and weak C-H center dot center dot center dot O hydrogen bonds involving the self-assembled 2-aminopyridinium pentamers, which are linked by C-H center dot center dot center dot pi and pi-pi stacking interactions. The most important contributions to the Hirshfeld surface arise from O center dot center dot center dot H/H center dot center dot center dot O (54.8%), H center dot center dot center dot H (17.8%) and C center dot center dot center dot H/H center dot center dot center dot C (13.4%) contacts.

引用

页码：1255 / +

页数：14

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