First we study the Gorenstein cohomological dimension Gcd(R)G of groups G over coefficient rings R, under changes of groups and rings; a characterization for finiteness of GcdRG is given. Some results in literature obtained over the coefficient ring Z or rings of finite global dimension are generalized to more general cases. Moreover, we establish a model structure on the weakly idempotent complete exact category Fib consisting of fibrant RG-modules, and show that the homotopy category Ho(Fib) is triangle equivalent to both the stable category Cof<overline>(RG) of Benson's cofibrant modules, and the stable module category StMod(RG) . The relation between cofibrant modules and Gorenstein projective modules is discussed, and we show that under some conditions such that Gcd(R)G<infinity , Ho(Fib) is equivalent to the stable category of Gorenstein projective RG-modules, the singularity category, and the homotopy category of totally acyclic complexes of projective RG-modules.