Light-Induced Iodine-Catalyzed Dealkylative Synthesis of Enaminones

被引：0

作者：

Zhao, Mingming ^{[1
]}

Wang, Luyao ^{[1
]}

Zhou, Yufeng ^{[1
]}

Guo, Fenke ^{[1
]}

Yang, Tao ^{[1
]}

Xiong, Heng-Ying ^{[1
]}

Wang, Teng ^{[2
]}

Zhang, Guangwu ^{[1
]}

机构：

[1] Henan Univ, Coll Chem & Chem Engn, Kaifeng 475004, Peoples R China

[2] Beijing Univ Chem Technol, Coll Chem, Beijing 100029, Peoples R China

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2024年 / 366卷 / 22期

关键词：

Enaminone; C-N bond Cleavage; Photocatalysis; Ynones;

D O I：

10.1002/adsc.202400631

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Light mediated iodine-catalyzed synthesis of enaminones through C-N bond cleavage has been described. In addition to substituted ynones, diverse substituted acyclic tertiary amines, and cyclic tertiary amines were also reactive under standard conditions. Selected transformations of the coupling adduct demonstrated the latent utility of this protocol. Preliminary mechanistic studies were also conducted.

引用

页码：4634 / 4638

页数：5

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