Sustainable Scalable Mechanochemical Synthesis of CdS/Bi2S3 Nanocomposites for Efficient Hydrogen Evolution

被引：0
|
作者：
Shalabayev, Zhandos [1 ,2 ]
Abilkhan, Abylay [1 ,2 ]
Khan, Natalya [1 ,2 ]
Tugelbay, Saparbek [1 ,2 ]
Seisembekova, Anar [1 ]
Tatykayev, Batukhan [2 ]
Balaz, Matej [3 ]
机构：
[1] al Farabi Kazakh Natl Univ, Dept Gen & Inorgan Chem, Alma Ata 050040, Kazakhstan
[2] Nazarbayev Univ, Natl Lab Astana, Astana 010000, Kazakhstan
[3] Slovak Acad Sci, Inst Geotech, Kosice 04001, Slovakia
来源：
NANOMATERIALS | 2024年 / 14卷 / 22期
关键词：
mechanochemistry; ball milling; semiconductor; cadmium sulfide; bismuth sulfide; hydrogen evolution; OPTICAL-PROPERTIES; RAMAN-SPECTRUM; BI2S3; HETEROSTRUCTURE; NANOSTRUCTURES; PHOTOCATALYSTS; NANOPARTICLES; PERFORMANCE; FABRICATION;
D O I：
10.3390/nano14221785
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In the present study, a green, scalable, and environmentally friendly approach was developed for the fabrication of Bi2S3-decorated CdS nanoparticles with an efficient hydrogen generation ability from the water. As a sulfur source, thiourea was used. The process was completed in two stages: mechanical activation and thermal annealing. The presence of spherical CdS nanoparticles and Bi2S3 nanorods in the CdS/Bi2S3 nanocomposite was confirmed and proved by XRD, Raman spectroscopy, SEM-EDS, and TEM. The synthesized CdS/Bi2S3 nanocomposites were evaluated for their photocatalytic hydrogen evolution capabilities. The CdS/Bi2S3 photocatalyst exhibited 25% higher photocatalytic activity compared to CdS, reaching a hydrogen evolution rate of 996.68 mu mol h-1g-1 (AQE 0.87%) after 3.5 h under solar-light irradiation.
引用
收藏
页数：18
相关论文
共 50 条
  • [31] Synthesis and growth mechanism of Bi2S3 nanoribbons
    Liu, ZP
    Liang, JB
    Li, S
    Peng, S
    Qian, Y
    CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (03) : 634 - 640
  • [32] Synthesis and thermoelectric properties of Bi2S3 nanobeads
    Fang, JY
    Chen, F
    Stokes, KL
    He, JB
    Tang, JK
    O'Connor, CJ
    MATERIALS FOR ENERGY STORAGE, GENERATION AND TRANSPORT, 2002, 730 : 119 - 124
  • [33] Mechanochemical Synthesis of Pyrenyl Graphdiyne Coupling CdS/CeO2, Constructing a Ternary Photocatalyst toward Efficient Hydrogen Evolution
    Liu, Yafeng
    Fan, Zhaobo
    Sun, Yantao
    Guo, Xin
    Jin, Zhiliang
    ACS APPLIED ENERGY MATERIALS, 2023, 6 (18) : 9743 - 9755
  • [34] Synthesis of monodispersed ultrafine Bi2S3 nanocrystals
    Shi, Lin
    Gu, Dong
    Li, Wei
    Han, Lu
    Wei, Hao
    Tu, Bo
    Che, Renchao
    JOURNAL OF ALLOYS AND COMPOUNDS, 2011, 509 (38) : 9382 - 9386
  • [35] Facile synthesis of Bi2S3 nanowire arrays
    Tang, C. J.
    Wang, G. Z.
    Wang, H. Q.
    Zhang, Y. X.
    Li, G. H.
    MATERIALS LETTERS, 2008, 62 (21-22) : 3663 - 3665
  • [36] Growth-regime-controlled synthesis of CdS-Bi2S3 and Bi2S3 nanocrystals during the dissolution-recrystallization processes
    He, Xiaobo
    Gao, Lian
    Yang, Songwang
    Sun, Jing
    CRYSTENGCOMM, 2010, 12 (11): : 3413 - 3418
  • [37] Enhancing Bi2S3 sensitised mesoporous TiO2 solar cells by co-sensitisation with Bi2S3/CdS quantum dots
    Annamalai, Alagappan
    Kim, Kyungho
    Jung, Kyungeun
    Lee, Man-Jong
    Ahn, Joon Mo
    INTERNATIONAL JOURNAL OF NANOTECHNOLOGY, 2016, 13 (4-6) : 354 - 364
  • [38] Studies of chemically deposited CdS:Bi2S3 mixed thin films
    Deshmukh, L. P.
    Holikatti, S. G.
    More, B. M.
    Rotti, C. B.
    Bulletin of Electrochemistry, 12 (3/4):
  • [39] Chemically grown Bi2S3 nanorod films for evolution
    Chalapathi, U.
    Reddy, B. Purushotham
    Sreekanth, T. V. M.
    Park, Si-Hyun
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2022, 47 (77) : 32796 - 32803
  • [40] Solid-State Reactions in CdS–Bi2S3 Thin Films
    V. N. Semenov
    O. V. Ostapenko
    A. N. Lukin
    E. I. Zavalishin
    A. Yu. Zavrazhnov
    Inorganic Materials, 2000, 36 : 1197 - 1199
12345