Catalytic development of boron and sulphur-doped g-C3N4 supported Cu-MOF composite for nitroarenes reduction reaction

Todays, the mesoporous heteroatom-doped materials were attracted the scientist interest due to their outstanding properties such as thermal/chemical stability, high specific surface area (SSA), facile synthetic protocol and also abundance precursor. So, in this study, the advanced and applicable Boron and Sulphur-doped g-C3N4 (g-BSCN) supported Cu-MOF (Cu@g-BSCN) was prepared via in situ growth of Cu-MOF on the surface of g-BSCN using H3BO3, thiourea, Cu(NO3)(2). 3H(2)O, and Terephthalic acid. The synergistic effect of B and S as the heteroatoms was triggered the plenty activated sites owing to the structural defect on the surface of the mesoporous g-BSCN. Moreover, the catalytic efficiency of g-BSCN was improved by in situ formation of copper-based MOF. The synthesized Cu@g-BSCN composite was utilized as the competent heterogenous catalyst in nitroarenes reduction in green and mild reaction condition (green solvent, and ambient temperature). High catalytic performance and desired recoverability are some of the benefits of this catalytic system.