Multi-role of K3V2(PO4)3/C nanocomposite as high-potential cathode materials for potassium ion battery with, antibacterial agent and visible-light-driven photocatalyst

被引:0
|
作者
Arunkumar, A. [1 ]
Anbarasan, P. M. [2 ]
Shkir, Mohd. [3 ]
Rajkumar, S. [4 ,5 ,6 ]
Sayed, M. A. [3 ]
机构
[1] Saveetha Univ, Saveetha Inst Med & Tech Sci, Saveetha Sch Engn, Dept Condensed Matter Phys, Chennai 602105, Tamil Nadu, India
[2] Periyar Univ, Dept Phys, Salem 636011, Tamil Nadu, India
[3] King Khalid Univ, Coll Sci, Dept Phys, Abha 61413, Saudi Arabia
[4] Henan Univ, Henan Key Lab Protect & Safety Energy Storage Ligh, Kaifeng 475004, Henan, Peoples R China
[5] Henan Univ, Henan Prov Engn Res Ctr Green Anticorros Technol M, Kaifeng 475004, Henan, Peoples R China
[6] Henan Univ, Coll Chem & Mol Sci, Kaifeng 475004, Henan, Peoples R China
关键词
Potassium-ion batteries; KVP/C composite; Cathode material; Photocatalyst; Environmental applications; Energy storage; ELECTRODE; ANODES;
D O I
10.1016/j.diamond.2025.112074
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Potassium-ion batteries are gaining popularity as viable options for economical and ecological energy storage systems. The advancement of potassium-ion batteries is sluggish owing to the substantial size of potassium ions, which complicates the design of suitable host materials. A hybrid of K3V2(PO4)3 (KVP) integrated with amorphous carbon (KVP/C) was synthesized using a simple organic-assisted approach. The samples' structural, morphological, and textural features were examined using XRD, FESEM, Raman spectroscopy, N2 isotherm, and XPS analysis. The K3V2(PO4)3/C bundled nanowires (BNS), characterized by a very stable framework, nano- porous structure, and conductive carbon covering, exhibit exceptional electrochemical performance in sodium- ion batteries. A consistent capacity of 125 mAh g- 1 may be attained at a rate of 100 mA g- 1. At a current density of 2000 mA g- 1, 97.2 % of the capacity is preserved after 5000 charge-discharge cycles. In comparison to KVP, the KVP/C BNS has markedly enhanced cycle stability. This study presents a simple and efficient method to improve the electrochemical performance of sodium-ion batteries. Following 60 min of direct solar illumination, the K3V2(PO4)3/C sample exhibited superior photodegradation efficiency against tetracycline (TC) antibiotics (92.7 % degradation), Rhodamine B (90.5 % degradation), methylene blue (88.5 % degradation), safranin-O (SO) (84.5 % degradation), and methyl red (MR) dyes (79.5 % degradation). It exhibited a greater zone of inhibitory activity (ZOI) against Staphylococcus aureus and Klebsiella pneumoniae. The recyclability trials with the K3V2(PO4)3/C catalyst shown improved durability through the fifth cycle. The findings of this research indicate that KVP nanoparticles may be beneficial across several fields, including antimicrobial materials, photocatalysis, and energy.
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页数:11
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