Cerium-Catalyzed Ritter-Type C-H Amination of Alkylarenes

被引：0

作者：

Guan, Renpeng ^{[1
]}

Wang, Tianlin ^{[1
]}

Bennett, Elliot L. ^{[1
]}

Huang, Zhiliang ^{[1
,2
]}

Xiao, Jianliang ^{[1
]}

机构：

[1] Univ Liverpool, Dept Chem, Liverpool L69 7Z, England

[2] Wuhan University, Sch Resource & Environm Sci, Hubei Biomass Resource Chem & Environm Biotechnol, Wuhan 430079, Peoples R China

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2025年 / 28卷 / 05期

基金：

英国工程与自然科学研究理事会;

关键词：

Ritter-type C-H amination; Amides; Alkylarenes; Nitriles; Cerium photocatalysis; CARBOXYLIC-ACIDS; C(SP(3))-H BONDS; VISIBLE-LIGHT;

D O I：

10.1002/ejoc.202400935

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reported here is a photocatalytic strategy for Ritter-type C-H amination of alkylarenes with nitriles. Under the irradiation of blue light and the catalysis of a simple Ce(III) salt, alkylarenes were brominated by CBr3COOH and thereby channeled to the normal Ritter pathway to afford amide products. A wide range of alkylarenes and nitriles were tolerated, with a few equivalents of a nitrile being feasible.

引用

页数：7

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