Ligand labilization gates intramolecular electron transfer in molecular photocatalyst

被引：0

作者：

Blechschmidt, Louis ^{[1
,2
]}

Zedler, Linda ^{[1
,2
]}

Mengele, Alexander K. ^{[3
]}

Rau, Sven ^{[3
]}

Dietzek-Ivansic, Benjamin ^{[1
,2
]}

机构：

[1] Friedrich Schiller Univ Jena, Inst Phys Chem, Helmholtzweg 4, D-07743 Jena, Germany

[2] Leibniz Inst Photon Technol IPHT, Dept Funct Interfaces, Albert Einstein Str 9, D-07745 Jena, Germany

[3] Ulm Univ, Inst Inorgan Chem 1, Albert Einstein Allee 11, D-89081 Ulm, Germany

来源：

CHEMICAL COMMUNICATIONS | 2025年 / 61卷 / 12期

关键词：

DINUCLEAR RU(II); CATALYTIC CENTER; CHARGE-TRANSFER; HYDROGEN; COMPLEXES; REDUCTION; RUTHENIUM; REGENERATION; PHOTOPHYSICS; MONONUCLEAR;

D O I：

10.1039/d4cc05844e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Identification of rate determining steps concerning catalyst activation and catalytic turnover is key to optimize molecular photocatalysts. In this contribution, femtosecond transient absorption spectroscopy upon variation of temperature and ionic strength yields new insights into the light-driven reactivity of the benchmark molecular photocatalyst, RutpphzRhCp*.

引用

页码：2508 / 2511

页数：4

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