Cobalt-catalyzed reduction of esters to alkanes

被引：0

作者：

Sahu, Manas Kumar ^{[1
]}

Pattanaik, Sandip ^{[1
]}

Gunanathan, Chidambaram ^{[1
]}

机构：

[1] OCC Homi Bhabha Natl Inst, Natl Inst Sci Educ & Res NISER, Sch Chem Sci, Bhubaneswar 752050, India

来源：

CHEMICAL COMMUNICATIONS | 2025年 / 61卷 / 08期

关键词：

HYDROGENATION; ALDEHYDES; ALCOHOLS; COMPLEXES; TRANSFORMATION; BIOMASS; ACIDS;

D O I：

10.1039/d4cc05364h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reduction of aryl carboxylates to methyl and allyl arene was attained using a well-defined cobalt catalyst. This catalytic transformation employs only a sub-stoichiometric amount of base, and diethylsilane as a reductant. Catalytic activation of the Si-H bond of the silanes, C-O bond of the ester, and silyl ether intermediates by cobalt is crucial to achieving exhaustive reduction.

引用

页码：1661 / 1664

页数：4

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