Neighboring Chalcogen Bonding for Controlling Dynamic Imine Chemistry in Aqueous Media

被引：0

作者：

Zhou, Yong ^{[1
,2
,3
]}

Zhang, Qinman ^{[1
,2
,3
]}

Jia, Shuaipeng ^{[2
,4
]}

Ye, Hebo ^{[2
]}

You, Lei ^{[2
,3
]}

机构：

[1] Fuzhou Univ, Coll Chem, Fuzhou 350108, Peoples R China

[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China

[3] Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Peoples R China

[4] Quanzhou Normal Univ, Coll Chem Engn & Mat Sci, Quanzhou 362000, Peoples R China

来源：

ORGANIC LETTERS | 2025年 / 27卷 / 10期

基金：

中国国家自然科学基金;

关键词：

SCHIFF-BASE; COVALENT CHEMISTRY; MULTIVALENCY; CATALYSIS;

D O I：

10.1021/acs.orglett.5c00359

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The impact of varied chalcogen bonds (sulfur, selenium, tellurium, and telluronium) on dynamic imine chemistry in aqueous solution is presented by introducing a carboxylate group or cationic telluronium into arylaldehydes. The role of chalcogen bonding in regulating the kinetics and thermodynamics of imine formation/exchange was elucidated through experimental and computational evidence, affording the largest effect for tellurium/telluronium compounds. By leveraging multivalent chalcogen bonding, telluronium-containing aldehyde enabled labeling of the N-terminus of amino acids in neutral buffer.

引用

页码：2438 / 2443

页数：6

共 50 条

[11] Controlling Chemistry in Dynamic Nanoscale Systems
Jesorka, Aldo
Lizana, Ludvig
Konkoli, Zoran
Czolkos, Ilja
Orwar, Owe
SINGLE MOLECULE SPECTROSCOPY IN CHEMISTRY, PHYSICS AND BIOLOGY, 2010, 96 : 449 - +
[12] Biomimetic Generation and Remodeling of Phospholipid Membranes by Dynamic Imine Chemistry
Seoane, Andres
Brea, Roberto J.
Fuertes, Alberto
Podolsky, Kira A.
Devaraj, Neal K.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2018, 140 (27) : 8388 - 8391
[13] Dynamic imine clipping self-assembly in polymer chemistry
Prokofjevs, Aleksandrs
Stoddart, J. Fraser
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 248
[14] Biobased dynamic hydrogels by reversible imine bonding for controlled release of thymopentin
Yu, Rui
Petit, Eddy
Barboiu, Mihail
Li, Suming
Sun, Wenjing
Chen, Congmei
MATERIALS SCIENCE & ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS, 2021, 127
[15] Sequence-specific association in aqueous media by integrating hydrogen bonding and dynamic covalent interactions
Li, Minfeng
Yamato, Kazuhiro
Ferguson, Joseph S.
Gong, Bing
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (39) : 12628 - 12629
[16] Recent perspective of antibiotics remediation: A review of the principles, mechanisms, and chemistry controlling remediation from aqueous media
Nkoh, Jackson Nkoh
Oderinde, Olayinka
Etafo, Nelson Oshogwue
Kifle, Ghebretensae Aron
Okeke, Emmanuel Sunday
Ejeromedoghenej, Onome
Mgbechidinma, Chiamaka Linda
Oke, Emmanuel A.
Raheem, Saheed Abiola
Bakare, Omonike Christianah
Ogunlaja, Olumuyiwa O.
Sindiku, Omotayo
Oladeji, Olatunde Sunday
SCIENCE OF THE TOTAL ENVIRONMENT, 2023, 881
[17] Problems of the ecological chemistry of aqueous media
Timaskev, S.
Russian Chemical Reviews, 1991, 60 (11) : 1181 - 1182
[18] A Hexavalent Tellurium-Based Chalcogen Bonding Catalysis Platform: High Catalytic Activity and Controlling of Selectivity
Li, Xinxin
Liu, Yi
Wang, Wei
Wang, Yao
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2025, 147 (04) : 3233 - 3242
[19] Intramolecular chalcogen bonding activated SuFEx click chemistry for efficient organic-inorganic linking
Wang, Minlong
Hou, Jiaman
Do, Hainam
Wang, Chao
Zhang, Xiaohe
Du, Ying
Dong, Qixin
Wang, Lijun
Ni, Ke
Ren, Fazheng
An, Jie
NATURE COMMUNICATIONS, 2024, 15 (01)
[20] Hydrogen Bonding Chemistry in Aqueous Ammonium Ion Batteries
Zhou, Mengmeng
Huang, Xinjun
Li, Hui
Duan, Xiaoguang
Zhao, Qin
Ma, Tianyi
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2024, 63 (46)

← 1 2 3 4 5 →