A novel route for the synthesis of phosphonate-containing siloxanes by the catalyst-free Kabachnik-Fields reaction

被引：0

作者：

Yang, Zhihui ^{[1
,2
,3
,4
]}

Wang, Xiaochen ^{[1
,2
,3
,4
]}

Wang, Yuanrong ^{[1
,2
,3
,4
]}

Yang, Jinyun ^{[1
,2
,3
,4
]}

Lu, Haifeng ^{[1
,2
,3
,4
]}

机构：

[1] Shandong Univ, Key Lab Special Funct Aggregated Mat, Jinan 250100, Shandong, Peoples R China

[2] Shandong Univ, Key Lab Colloid & Interface Chem Minist Educ, Jinan 250100, Shandong, Peoples R China

[3] Shandong Key Lab Adv Organosilicon Mat & Technol, Jinan, Shandong, Peoples R China

[4] Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Shandong, Peoples R China

来源：

RUSSIAN CHEMICAL BULLETIN | 2024年 / 73卷 / 09期

关键词：

siloxanes; amino phosphonates; catalyst-free reactions; Kabachnik-Fields reaction; organophosphorus compounds; organosilicon compounds; ONE-POT SYNTHESIS; ALPHA-AMINOPHOSPHONATES; ALDEHYDES;

D O I：

10.1007/s11172-024-4385-5

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new route for the synthesis of siloxanes containing substituents with the phosphonate and amino groups based on the catalyst-free Kabachnik-Fields reaction was developed. The synthesis was accomplished under mild conditions using 3-aminopropylsilanes, cyclic ketones, and diethyl phosphite as the starting materials to give the corresponding 1-(3-silylpropylamino)cycloalkylphosphonates in high yields.

引用

页码：2725 / 2729

页数：5

共 50 条

[21] Camphor-derived thioureas: Synthesis and application in asymmetric Kabachnik-Fields reaction
Reddy, Pogula Sreekanth
Reddy, Motakatla Venkata Krishna
Reddy, Peddiahgari Vasu Govardhana
CHINESE CHEMICAL LETTERS, 2016, 27 (06) : 943 - 947
[22] First synthesis of α-aminophosphonates from natural porphyrin derivatives by the Kabachnik-Fields reaction
Kabachnic, MM
Zobnina, EV
Pavlov, VV
Konstantinov, IO
Ponomarev, GV
Beletskaya, IP
RUSSIAN CHEMICAL BULLETIN, 2005, 54 (01) : 262 - 265
[23] Microwave-assisted synthesis of -aminophosphonates and related derivatives by the Kabachnik-Fields reaction
Tajti, Adam
Balint, Erika
Keglevich, Gyorgy
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2019, 194 (4-6) : 379 - 381
[24] Synthesis of covalent organic frameworks via Kabachnik-Fields reaction for water treatment
Wu, Wen-Xiu
Li, Fei
Yao, Bing-Jian
Ding, Luo-Gang
Kan, Jing-Lan
Liu, Fei
Zhao, Guo-Yan
Wang, Song
Dong, Yu-Bin
JOURNAL OF HAZARDOUS MATERIALS, 2022, 433
[25] Synthesis of phosphoric acid supported on magnetic core-shell nanoparticles: a novel recyclable heterogeneous catalyst for Kabachnik-Fields reaction in water
Sobhani, Sara
Falatooni, Zahra Mesbah
Honarmand, Moones
RSC ADVANCES, 2014, 4 (30) : 15797 - 15806
[26] Camphor-derived thioureas: Synthesis and application in asymmetric Kabachnik-Fields reaction
Pogula Sreekanth Reddy
Motakatla Venkata Krishna Reddy
Peddiahgari Vasu Govardhana Reddy
Chinese Chemical Letters, 2016, 27 (06) : 943 - 947
[27] T3P®-promoted Kabachnik-Fields reaction: an efficient synthesis of α-aminophosphonates
Milen, Matyas
Abranyi-Balogh, Peter
Dancso, Andras
Frigyes, David
Pongo, Laszlo
Keglevich, Gyoergy
TETRAHEDRON LETTERS, 2013, 54 (40) : 5430 - 5433
[28] Iodine Catalyzed Kabachnik-Fields Reaction of Trialkyl Phosphites: Facile Access to Benzoxazine Containing Phosphorus
Wang, Yufeng
Yang, Yajie
Huang, Ling
Jie, Kun
Guo, Shengmei
Cai, Hu
CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2017, 37 (12) : 3220 - 3228
[29] Tin(II) Compounds as Catalysts for the Kabachnik-Fields Reaction under Solvent-Free Conditions: Facile Synthesis of α-Aminophosphonates
Gallardo-Macias, Ricardo
Nakayama, Kensaku
SYNTHESIS-STUTTGART, 2010, (01): : 57 - 62
[30] Choline chloride•2ZnCl2 ionic liquid: an efficient and reusable catalyst for the solvent free Kabachnik-Fields reaction
Disale, Shamrao T.
Kale, Sandip R.
Kahandal, Sandeep S.
Srinivasan, Thandankorai G.
Jayaram, Radha V.
TETRAHEDRON LETTERS, 2012, 53 (18) : 2277 - 2279

← 1 2 3 4 5 →