New ferrocene- and ruthenocene-based nickel pincer complexes

被引：0
|
作者：
Safronov, S. V. [1 ]
Kuklin, S. A. [1 ]
Abramova, N. V. [1 ]
Nelyubina, Yu. V. [1 ]
机构：
[1] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Bldg 1,28 ul Vavilova, Moscow 119334, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2024年 / 73卷 / 10期
基金：
俄罗斯科学基金会;
关键词：
nickel; pincer; complex; ferrocene; ruthenocene; metallocene; diphosphine; ligand; CARBON-DIOXIDE; HYDRIDE COMPLEXES; PALLADIUM; IRIDIUM; REACTIVITY; REDUCTION; CATALYSTS; CRYSTAL; RHODIUM; LIGAND;
D O I：
10.1007/s11172-024-4399-z
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
First ferrocene- and ruthenocene-based nickel pincer complexes, NiCl[{2,5-(But2PCH2)2C5H2}Fe(C5H5)] (3a) and NiCl[{2,5-(But2PCH2)2C5H2}Ru(C5H5)] (3b), respectively, were synthesized and characterized by 1H, 31P{1H}, and 13C{1H} NMR spectroscopy. The structure of complex 3b was established by single-crystal X-ray diffraction.
引用
收藏
页码：2831 / 2837
页数：7
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