Adaptation of (h, T) Data To Calculate Some Thermodynamic Properties of SF6 on the Saturation Curve

被引:0
|
作者
Ustyuzhanin, E. E. [1 ]
Ochkov, V. F. [1 ]
Rykov, S. V. [2 ]
Kudryavtseva, I. V. [2 ]
Rykov, V. A. [2 ]
机构
[1] MPEI Natl Res Univ, Moscow, Russia
[2] ITMO Univ, St Petersburg, Russia
关键词
saturation line; density; sulfur hexafluoride; order parameter; rectilinear diameter; LINE;
D O I
10.1134/S199079312470101X
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
Information is presented on the behavior of the SF6 density on the binodal in the asymptotic vicinity of the critical point 3 x 10(-6) < tau < 2 x 10(-4), where tau = (T-c - T)/T-c is the relative temperature, and T-c is the critical temperature. The densities of the liquid (rho(l)) and vapor (rho(g)) phases were calculated based on the experimental data of Garrabos et al. (2018) on the height h at which the meniscus is located separating the two phases of the sample in a horizontal cell of diameter d at a temperature T under the terrestrial gravity. The second component of the method was the order parameter f(s)(tau) in an analytical form, which meets conditions of the scaling theory (ST) of critical phenomena and is based on the (rho(l), rho(g), T) data of Funke et al. (1998) on SF6 in the range of 10(-3) < tau < 0.3. A number of problems were formulated, including the construction of the dependences rho(l)(tau) and rho(g)(tau) those are consistent with ST and correlate with the (h, T) data at 10(-6) < tau < 10(-3). The relationship was studied between the (h, T) data and the functions f(s)(tau) and f(d)(tau) (f(d) is the average or rectilinear diameter). The temperatures dependences of rho(l) and rho(g) were constructed in the range of 10(-6) < tau < 10(-3) .
引用
收藏
页码:1721 / 1728
页数:8
相关论文
共 46 条
  • [21] Calculation of thermodynamic properties of SF6 including the critical region. Combined thermal equation of state with a small number of parameters
    P. P. Bezverkhii
    V. G. Martynets
    A. B. Kaplun
    A. B. Meshalkin
    High Temperature, 2017, 55 : 693 - 701
  • [22] Calculation of thermodynamic properties of SF6 including the critical region. Combined thermal equation of state with a small number of parameters
    Bezverkhii, P. P.
    Martynets, V. G.
    Kaplun, A. B.
    Meshalkin, A. B.
    HIGH TEMPERATURE, 2017, 55 (05) : 693 - 701
  • [23] Influence of Copper Contamination on Equilibrium Compositions, Thermodynamic Properties, Transport Coefficients, and Combined Diffusion Coefficients of High-temperature SF6 Gas
    Zhong, Linlin
    Wang, Xiaohua
    Wu, Yi
    Rong, Mingzhe
    Zhang, Xin
    Xiang, Zhen
    Zhao, Yuming
    Liu, Shungui
    2015 3RD INTERNATIONAL CONFERENCE ON ELECTRIC POWER EQUIPMENT - SWITCHING TECHNOLOGY (ICEPE-ST), 2015, : 321 - 324
  • [24] Using molecular dynamic simulation data of calcite in a wide pressure range to calculate some of its thermodynamic properties via some universal equations of state
    Akbarzadeh, Hamed
    Shokouhi, Mohammad
    Parsafar, Gholam Abbas
    MOLECULAR PHYSICS, 2008, 106 (21-23) : 2545 - 2556
  • [25] A Reference Equation of State for the Thermodynamic Properties of Sulfur Hexafluoride (SF6) for Temperatures from the Melting Line to 625 K and Pressures up to 150 MPa
    Guder, C.
    Wagner, W.
    JOURNAL OF PHYSICAL AND CHEMICAL REFERENCE DATA, 2009, 38 (01) : 33 - 94
  • [26] Optimisation of a home-made RIE system -: Effect of SF6 plasma on the properties of partially etched a-Si:H films
    Pereira, P
    Lavareda, G
    do Rego, AMB
    Amaral, A
    de Carvalho, CN
    ADVANCED MATERIALS FORUM II, 2004, 455-456 : 124 - 127
  • [27] SOME SALIENT FEATURES OF A DOUBLE DISCHARGE HF CHEMICAL-LASER USING SF6 AND C3H8 MIXTURE
    JUYAL, DP
    JOURNAL OF THE OPTICAL SOCIETY OF AMERICA, 1978, 68 (05) : 674 - 674
  • [28] Stabilität des postoperativen Visus nach rt-PA-SF6-Behandlung der submakulären Hämorrhagie bei altersabhängiger MakuladegenerationStability of postoperative visual acuity after treatment of submacular hemorrhage with rt-PA and SF6(SF6) in age-related macular degeneration
    A. Steller
    E. Gerke
    Der Ophthalmologe, 2004, 101 : 500 - 504
  • [29] Electrical properties of 4H-SiC thin films reactively ion-etched in SF6/O2 plasma
    Kim, BS
    Jeong, JK
    Um, MY
    Na, HJ
    Song, IB
    Kim, HJ
    SILICON CARBIDE AND RELATED MATERIALS 2001, PTS 1 AND 2, PROCEEDINGS, 2002, 389-3 : 953 - 956
  • [30] Electrospun ZnO-SnO2 Composite Nanofibers and Enhanced Sensing Properties to SF6 Decomposition Byproduct H2S
    Lu, Zhaorui
    Zhou, Qu
    Wang, Caisheng
    Wei, Zhijie
    Xu, Lingna
    Gui, Yingang
    FRONTIERS IN CHEMISTRY, 2018, 6