1,3-Butadiene formation through selective acetylene electrolysis on partially oxidized copper

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10.1038/s41929-024-01255-9
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Conventional thermocatalytic routes to 1,3-butadiene are energy intensive. Now, a method for the selective electroreduction of acetylene to 1,3-butadiene under ambient conditions is demonstrated. Use of an iodide-containing electrolyte stabilizes partially oxidized copper sites on the catalyst, facilitating the synthesis of 1,3-butadiene with a Faradaic efficiency of up to 93%.
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页码:1268 / 1269
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