Research progress of SCR medium temperature denitrification catalyst for cement industry

被引:0
|
作者
Han Y. [1 ]
Zhou Y. [1 ]
Tan C. [1 ]
Wu P. [1 ]
Ding S. [1 ]
Shen K. [1 ]
Zhang Y. [1 ]
机构
[1] Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, School of Energy and Environment, Southeast University, Nanjing
关键词
alkali metal; cement denitration; de NO[!sub]x[!/sub; selective catalytic reduction;
D O I
10.19906/j.cnki.JFCT.2023084
中图分类号
学科分类号
摘要
Selective catalytic reduction (SCR) technology has been widely used in the denitrification of cement industry, in which a relatively mature system has been formed in the high temperature (280 –350 ℃) section, but there is still a breakthrough in the middle temperature zone. Focusing on medium temperature catalysts, this paper reviewed the progress of Mn, Ce and V catalysts, and analyzed the doping of Sm, Nb, Ho, Sb, La, Mo and Pr to improve the performance of catalysts. Combined with the characteristics of the high content of SO2, H2O and alkali metal in cement kiln smoke, the causes of catalyst poisoning were analyzed, and the way to resist sulfur poisoning, water poisoning, and alkali metal poisoning was summarized. The research prospect of SCR medium temperature denitration catalyst in cement industry is prospected. © 2024 Science Press. All rights reserved.
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页码:756 / 774
页数:18
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  • [11] LIU F, SHAN W, SHI X, Et al., Research progress in vanadium-free catalysts for the selective catalytic reduction of NO with NH3[J], Chin J Catal, 32, 7, (2011)
  • [12] LIU Xingyu, ZHANG Peng, JIA Yuanyuan, Et al., Research progress of low-temperature SCR denitration catalysts based on TiO2 support[J], Environ Prot Chem Ind, 40, 1, pp. 26-31, (2020)
  • [13] MA Yingli, GAO Fengyu, JIA Guangru, Et al., Review on the development, application and forming process of SCR denitration catalyst[J], Mod Chem Ind, 39, 8, pp. 33-37, (2019)
  • [14] ZHANG Tao, DENG Lifeng, CHEN Jiajun, Et al., Progress in the application of SCR denitrification technology in the flue gas treatment of cement kiln[J], Environ Technol, 27, 6, pp. 61-64, (2021)
  • [15] LU Hao, YIN Tao, Application prospect of new manganese based ultra-low temperature SCR technology in cement kiln[J], China Cement, 11, pp. 63-66, (2022)
  • [16] WANG Hai, HAN Chen, Research on SCR denitrification technology of cement kiln flue gas[J], Energy Technol, 21, 4, pp. 93-96, (2023)
  • [17] CHENG Qun, YUAN Zijian, Engineering application of SCR denitrification technology in cement kiln, Cement, 4, pp. 17-23, (2023)
  • [18] ZHANG Xing, LIANG Lipeng, CHEN Hongsheng, Et al., Analysis of the actual running data of the medium temperature and medium dust SCR denitration technology in cement plant, Cement Eng, 6, (2022)
  • [19] ZHANG Zhenkun, LU Chunlin, WANG Lan, Application of medium temperature and medium dust SCR denitrification technology in cement kiln production line[J], Cement, 9, pp. 29-31, (2022)
  • [20] SHENG Bin, DUAN Zhenhong, WANG Lan, Technology and engineering application case analysis of medium and low temperature SCR denitration catalyst[J], Cement, 1, pp. 18-22, (2023)