Research progress of SCR medium temperature denitrification catalyst for cement industry

被引：0
|
作者：
Han Y. [1 ]
Zhou Y. [1 ]
Tan C. [1 ]
Wu P. [1 ]
Ding S. [1 ]
Shen K. [1 ]
Zhang Y. [1 ]
机构：
[1] Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, School of Energy and Environment, Southeast University, Nanjing
来源：
Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology | 2024年 / 52卷 / 05期
关键词：
alkali metal; cement denitration; de NO[!sub]x[!/sub; selective catalytic reduction;
D O I：
10.19906/j.cnki.JFCT.2023084
中图分类号：
学科分类号：
摘要：
Selective catalytic reduction (SCR) technology has been widely used in the denitrification of cement industry, in which a relatively mature system has been formed in the high temperature (280 –350 ℃) section, but there is still a breakthrough in the middle temperature zone. Focusing on medium temperature catalysts, this paper reviewed the progress of Mn, Ce and V catalysts, and analyzed the doping of Sm, Nb, Ho, Sb, La, Mo and Pr to improve the performance of catalysts. Combined with the characteristics of the high content of SO2, H2O and alkali metal in cement kiln smoke, the causes of catalyst poisoning were analyzed, and the way to resist sulfur poisoning, water poisoning, and alkali metal poisoning was summarized. The research prospect of SCR medium temperature denitration catalyst in cement industry is prospected. © 2024 Science Press. All rights reserved.
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页码：756 / 774
页数：18
相关论文
共 157 条
  • [1] Economic Operation Report of China cement industry in 2019[J], Guangdong Building Materials, 36, 1, pp. 76-78, (2020)
  • [2] LI Haibo, LEI Hua, LI Lingxiao, Application of SCR denitrification technology in cement kiln flue gas[J], China Cement, 201, pp. 84-86, (2019)
  • [3] ZHANG Ling-hui, Study on Influencing factors and source prevention of fuel type NOx formation in cement decomposing furnace, (2016)
  • [4] CHEN Bolin, China Cement economic Operation in 2022 and Outlook in 2023[J], China Cement, 2, pp. 6-10, (2023)
  • [5] ZHANG Daojun, MA Ziran, WANG Baodong, Et al., Application of SCR denitrification technology in flue gas treatment of non-electric industry[J], Mod Chem Ind, 39, 10, pp. 24-28, (2019)
  • [6] DONG Bei, GAO Min, Development and application of SCR denitration system in cement kiln.[J], Cement Guide New Epoch, 27, 1, pp. 74-77, (2021)
  • [7] LIAO Yuyun, MAO Zhiwei, GAN Hao, Et al., Research and application of low-temperature SCR catalyst for flue gas denitrification in cement kilns[J], China Cement, 8, pp. 84-86, (2016)
  • [8] XIAODONG W U, LEE H R, LIU S, Et al., Sulfur poisoning and regeneration of MnOx -CeO2 -Al2O3 catalyst for soot oxidation[J], J Rare Earth, 30, 7, (2012)
  • [9] ZHANG Bolin, ZHANG Shengyang, ZHANG Shengen, Application of rare earth elements in denitrification catalysts[J], Prog Chem, 34, 2, pp. 301-318, (2022)
  • [10] XIE Yuxian, LIU Tao, SU Sheng, Et al., Effect of oxygen content in flue gas of industrial kiln on NH3-SCR denitrification reaction of vanadium titanium catalysts[J], CIESC J, 73, 10, (2022)
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