Preparation of Ni0.6Cu0.4O/NC catalyst and its catalytic performance for hydrogen production from hydrolysis of ammonia borane

被引：0
|
作者：
Li, Rong [1 ]
Zuo, Youhua [1 ]
Hua, Junfeng [2 ]
Hao, Siyu [1 ]
Xu, Lixin [1 ]
Ye, Mingfu [1 ,3 ,4 ]
Wan, Chao [1 ,4 ,5 ,6 ]
机构：
[1] School of Chemistry and Chemical Engineering, Anhui University of Technology, Ma’anshan,243032, China
[2] Zhejiang Environment Technology Co., Ltd, Hangzhou,310027, China
[3] Engineering Research Center of Biofilm Water Purification and Utilization Technology of Ministry of Education, Anhui University of Technology, Ma’anshan,243032, China
[4] Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin,300071, China
[5] Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Changzhou University, Changzhou,213164, China
[6] College of Chemical Engineering and Biological Engineering, Zhejiang University, Hangzhou,310058, China
来源：
Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology | 2024年 / 52卷 / 08期
基金：
中国国家自然科学基金;
关键词：
Ammonia borane - Carbon material - Catalytic performance - Highest temperature - Hydrogen hydrolysis - Hydrogen storage capacities - Nitrogen-containing carbon material - Nitrogen-containing carbons - Order reactions - ]+ catalyst;
D O I：
10.1016/S1872-5813(24)60436-6
中图分类号：
学科分类号：
摘要：
Ammonia borane (NH3BH3, AB) is an ideal feedstock with high hydrogen storage capacity. In this paper, nitrogen-containing carbon material (Ni0.6Cu0.4O/NC) catalyst was prepared by high-temperature carbonization of Ni/Cu-ZIF precursor under nitrogen atmosphere. The microstructure as well as the composition of the as-prepared catalyst were characterized. In addition, the catalytic performance of the catalyst were tested under reaction conditions. The results showed that the activation energy (Ea) for hydrolysis of AB over Ni0.6Cu0.4O/NC catalyst was 56.8 kJ/mol with TOF value as high as 1572.2 h−1. The hydrogen production could be approximated as a zero-order reaction with respect to the concentration of AB, and a one-order reaction with respect to the amount of catalyst. The catalyst still maintained good activity after ten cycles, indicating the good stability. © 2024 Science Press. All rights reserved.
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页码：1184 / 1192
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