Are spodium bonds directional?

被引：0

作者：

Boro, Velina R. ^{[1
]}

Saha, Binoy K. ^{[1
]}

Rangazhvar, Gurudosguptha ^{[1
]}

机构：

[1] Pondicherry Univ, Dept Chem, Pondicherry 605014, India

来源：

CHEMICAL COMMUNICATIONS | 2025年 / 61卷 / 05期

关键词：

CORRECTED STATISTICAL-ANALYSIS; DER-WAALS RADII; SIGMA-HOLE; CRYSTAL-STRUCTURES; HYDROGEN-BONDS; PI; COMPLEXES; GEOMETRY; HALOGEN; VAN;

D O I：

10.1039/d4cc05789a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Statistical analyses and computational studies have been performed on spodium bonds with four- and five-coordinated spodium complexes. Though statistical analyses without geometry correction suggest that the most populous geometries are far from linearity, geometry-corrected analyses suggest that these bonds are directional and linear. Computational studies suggest that the bond strength can be moderately strong.

引用

页码：945 / 948

页数：4

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