Are spodium bonds directional?

被引：0

作者：

Boro, Velina R. ^{[1
]}

Saha, Binoy K. ^{[1
]}

Rangazhvar, Gurudosguptha ^{[1
]}

机构：

[1] Pondicherry Univ, Dept Chem, Pondicherry 605014, India

来源：

CHEMICAL COMMUNICATIONS | 2025年 / 61卷 / 05期

关键词：

CORRECTED STATISTICAL-ANALYSIS; DER-WAALS RADII; SIGMA-HOLE; CRYSTAL-STRUCTURES; HYDROGEN-BONDS; PI; COMPLEXES; GEOMETRY; HALOGEN; VAN;

D O I：

10.1039/d4cc05789a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Statistical analyses and computational studies have been performed on spodium bonds with four- and five-coordinated spodium complexes. Though statistical analyses without geometry correction suggest that the most populous geometries are far from linearity, geometry-corrected analyses suggest that these bonds are directional and linear. Computational studies suggest that the bond strength can be moderately strong.

引用

页码：945 / 948

页数：4

共 50 条

[1] Single-electron spodium bonds: Substituent effects
Wu, Qiaozhuo
McDowell, Sean A. C.
Li, Qingzhong
APPLIED ORGANOMETALLIC CHEMISTRY, 2023, 37 (04)
[2] Study of Beryllium, Magnesium, and Spodium Bonds to Carbenes and Carbodiphosphoranes
Jablonski, Miroslaw
MOLECULES, 2021, 26 (08):
[3] Spodium Bonds: Noncovalent Interactions Involving Group 12 Elements
Bauza, Antonio
Alkorta, Ibon
Elguero, Jose
Mooibroek, Tiddo J.
Frontera, Antonio
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59 (40) : 17482 - 17487
[4] Spodium and tetrel bonds involving Zn(II)/Cd(II) and their interplay
Liu, Na
Li, Qingzhong
Scheiner, Steve
CHEMICAL PHYSICS, 2022, 556
[5] Imparting bonds, directional bonds
不详
PHOTONICS SPECTRA, 2013, 47 (01) : 24 - 24
[6] Intramolecular Spodium Bonds in Zn(II) Complexes: Insights from Theory and Experiment
Karmakar, Mainak
Frontera, Antonio
Chattopadhyay, Shouvik
Mooibroek, Tiddo J.
Bauza, Antonio
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES, 2020, 21 (19) : 1 - 14
[7] Differentiating intramolecular spodium bonds from coordination bonds in two polynuclear zinc(ii) Schiff base complexes
Basak, Tanmoy
Gomila, Rosa M.
Frontera, Antonio
Chattopadhyay, Shouvik
CRYSTENGCOMM, 2021, 23 (14) : 2703 - 2710
[8] Spodium Bonds in Biological Systems: Expanding the Role of Zn in Protein Structure and Function
Biswal, Himansu S.
Sahu, Akshay Kumar
Frontera, Antonio
Bauza, Antonio
JOURNAL OF CHEMICAL INFORMATION AND MODELING, 2021, 61 (08) : 3945 - 3954
[9] Directional Ionic Bonds
Hutskalov, Illia
Linden, Anthony
Coric, Ilija
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2023, 145 (15) : 8291 - 8298
[10] Hg(II).d8[M] Interactions: Are they Metallophilic Interactions or Spodium Bonds?
Burguera, Sergi
Bauza, Antonio
Frontera, Antonio
CHEMPHYSCHEM, 2023, 24 (24)

← 1 2 3 4 5 →