Ni(<sc>ii</sc>)-catalyzed nucleophilic substitution for the synthesis of allenylselenide

被引：0

作者：

Zeng, Ling-Hong ^{[1
]}

Cui, Ranran ^{[1
]}

Huang, Zhuo ^{[1
]}

Zhang, Qing-Wei ^{[1
]}

机构：

[1] Univ Sci & Technol China, Dept Chem, Key Lab Precis & Intelligent Chem, Hefei 230026, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2025年 / 61卷 / 06期

关键词：

CHEMISTRY; PALLADIUM; SELENIUM;

D O I：

10.1039/d4cc05065g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A method for synthesizing allenylselenides has been developed using readily available propargyl carbonate and phenylselenol. The reaction is catalyzed by Ni(ii) and proceeds via a migratory insertion and beta-oxygen elimination mechanism. Due to the strong interaction between Se and Ni leading to catalyst deactivation, zinc salt was used to mitigate the deleterious effects of Se anions on the catalyst, thereby facilitating the successful synthesis of the target products.

引用

页码：1192 / 1195

页数：4

共 50 条

[41] Visible light-induced ruthenium(<sc>ii</sc>)-catalyzed hydroarylation of unactivated olefins
Trienes, Sven
Golling, Stephane
Gieuw, Matthew H.
Di Matteo, Marco
Ackermann, Lutz
CHEMICAL SCIENCE, 2024, 15 (45) : 19037 - 19043
[42] Recent advances in the application of calcium(<sc>ii</sc>) triflimide in organic synthesis
Li, Haoran
Kuang, Minyao
Liu, Yuwei
Yi, Wei
Wang, Shengdong
ORGANIC CHEMISTRY FRONTIERS, 2025, 12 (04): : 1355 - 1373
[43] Complexation of drug amifampridine with Cu(<sc>ii</sc>), Zn(<sc>ii</sc>) and Cd(<sc>ii</sc>) ions, and its dimerization with the magic of Mn(<sc>ii</sc>) salts. Potential anti-COVID-19 and anticancer activities
Hajibabaei, Farshid
Movafagh, Samaneh Sanei
Salehzadeh, Sadegh
Gable, Robert William
DALTON TRANSACTIONS, 2024, 53 (03) : 1066 - 1086
[44] Diacylthioureas - an overlooked class of ligands; the coordination chemistry of diacylated thiourea with platinum(<sc>ii</sc>), palladium(<sc>ii</sc>) and gold(<sc>iii</sc>)
Risi, Matthew C.
Atiga, Simeon
Christopher, Timothy D.
Henderson, William
Saunders, Graham C.
DALTON TRANSACTIONS, 2025, 54 (12) : 4977 - 4989
[45] Detailed mechanism of a DNA/RNA nucleobase substituting bridging ligand in diruthenium(<sc>ii</sc>,<sc>iii</sc>) and dirhodium(<sc>ii</sc>,<sc>ii</sc>) tetraacetato paddlewheel complexes: protonation of the leaving acetate is crucial
Tolbatov, Iogann
Marzo, Tiziano
Umari, Paolo
La Mendola, Diego
Marrone, Alessandro
DALTON TRANSACTIONS, 2025, 54 (02) : 662 - 673
[46] Diacylthioureas - an overlooked class of ligands; the coordination chemistry of diacylated thiourea with platinum(<sc>ii</sc>), palladium(<sc>ii</sc>) and gold(<sc>iii</sc>)
Risi, Matthew C.
Atiga, Simeon
Christopher, Timothy D.
Henderson, William
Saunders, Graham C.
DALTON TRANSACTIONS, 2025,
[47] Synthesis of thiocarbonyl analogues of colourimetric coumarin-based chemosensors: altering the selectivity from Fe to Hg(<sc>ii</sc>) and Cu(<sc>ii</sc>) ions
Schoeman, Stiaan
Mama, Neliswa
Myburgh, Lisa
NEW JOURNAL OF CHEMISTRY, 2025, 49 (05) : 1745 - 1754
[48] Reversal of enantioselectivity in cobalt(<sc>ii</sc>)-catalyzed asymmetric Michael-alkylation reactions: synthesis of spiro-cyclopropane-oxindoles
Zhang, Jun-Hao
Yang, Wei-Jing
Li, Ning
Tian, Yin
Xie, Ming-Sheng
Guo, Hai-Ming
ORGANIC CHEMISTRY FRONTIERS, 2024, 11 (14): : 4007 - 4013
[49] Nickel(<sc>ii</sc>)-hydrazineylpyridine catalyzed regioselective synthesis of α-benzyl substituted β-hydroxy ketones via a Fenton free radical reaction
Singh, Apurva
Ahmed, Naseem
ORGANIC & BIOMOLECULAR CHEMISTRY, 2025, 23 (07) : 1689 - 1695
[50] Efficient and chemoselective imine synthesis catalyzed by a well-defined PN3-manganese(<sc>ii</sc>) pincer system
Gholap, Sandeep Suryabhan
Al Dakhil, Abdullah
Chakraborty, Priyanka
Dighe, Shashikant
Rahman, Mohammad Misbahur
Dutta, Indranil
Hengne, Amol
Huang, Kuo-Wei
CHEMICAL COMMUNICATIONS, 2024, 60 (19) : 2617 - 2620

← 1 2 3 4 5 →