Ni(<sc>ii</sc>)-catalyzed nucleophilic substitution for the synthesis of allenylselenide

被引：0

作者：

Zeng, Ling-Hong ^{[1
]}

Cui, Ranran ^{[1
]}

Huang, Zhuo ^{[1
]}

Zhang, Qing-Wei ^{[1
]}

机构：

[1] Univ Sci & Technol China, Dept Chem, Key Lab Precis & Intelligent Chem, Hefei 230026, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2025年 / 61卷 / 06期

关键词：

CHEMISTRY; PALLADIUM; SELENIUM;

D O I：

10.1039/d4cc05065g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A method for synthesizing allenylselenides has been developed using readily available propargyl carbonate and phenylselenol. The reaction is catalyzed by Ni(ii) and proceeds via a migratory insertion and beta-oxygen elimination mechanism. Due to the strong interaction between Se and Ni leading to catalyst deactivation, zinc salt was used to mitigate the deleterious effects of Se anions on the catalyst, thereby facilitating the successful synthesis of the target products.

引用

页码：1192 / 1195

页数：4

共 50 条

[1] Recovery of Co(<sc>ii</sc>), Ni(<sc>ii</sc>) and Zn(<sc>ii</sc>) using magnetic nanoparticles (MNPs) at circumneutral pH
O'Neill, Katie E. B.
Biswakarma, Jagannath
Crane, Rich
Byrne, James M.
ENVIRONMENTAL SCIENCE-NANO, 2025, 12 (04) : 2371 - 2382
[2] Dearomatized diimines for nickel(<sc>ii</sc>) and palladium(<sc>ii</sc>) catalyzed ethylene polymerization and copolymerization
Guo, Lihua
Zhao, Wei
Ji, Mingjun
Chen, Weiqiang
Li, Pengwei
Li, Lijie
Li, Jiaxing
Liu, Zhe
INORGANIC CHEMISTRY FRONTIERS, 2024, 11 (05) : 1394 - 1412
[3] Ni(<sc>ii</sc>)/spiroBox-catalyzed asymmetric Friedel-Crafts alkylation of indoles with nitroalkenes
Li, Yanshun
Sun, Shiqin
Jiao, Luzhen
Gao, Nanxing
Cao, Guorui
RSC ADVANCES, 2025, 15 (10) : 7644 - 7648
[4] Tuning the organic ligands to optimize the nitrogen reduction performance of Co(<sc>ii</sc>) or Ni(<sc>ii</sc>)-based MOFs
Qin, Ling
Zhao, Ying-Xin
Liu, Qiang
An, Jin-Long
Wang, Han-Xi
Zhang, Mao-Feng
Shi, Cheng-Wu
Zheng, He-Gen
MATERIALS CHEMISTRY FRONTIERS, 2024, 8 (19) : 3203 - 3213
[5] A Pd(<sc>ii</sc>)-catalyzed denitrative alkyne annulation reaction for the synthesis of cyclopenta[b]chromanes
Bhorali, Pratiksha
Kalita, Deep J.
Das, Babulal
Gogoi, Sanjib
ORGANIC CHEMISTRY FRONTIERS, 2024, 11 (10) : 2834 - 2838
[6] Synthesis and structure of copper(<sc>ii</sc>) and manganese(<sc>ii</sc>) diethylmalonates with 4,4′-bipyridine
Chistyakov, A. S.
Knyazev, D. A.
Zorina-Tikhonova, E. N.
Kiskin, M. A.
Vologzhanina, A. V.
Eremenko, I. L.
RUSSIAN CHEMICAL BULLETIN, 2024, 73 (10) : 2838 - 2843
[7] Synthesis, characterization, biological evaluation, DFT and molecular docking studies of (Z)-2-((2-bromo-4-chlorophenyl)imino)methyl)-4-chlorophenol and its Co(<sc>ii</sc>), Ni(<sc>ii</sc>), Cu(<sc>ii</sc>), and Zn(<sc>ii</sc>) complexes
Waziri, Ibrahim
Masena, Hlonepho M.
Yusuf, Tunde L.
Coetzee, Louis-Charl C.
Adeyinka, Adedapo S.
Muller, Alfred J.
NEW JOURNAL OF CHEMISTRY, 2023, 47 (38) : 17853 - 17870
[8] Synthesis and anion binding properties of (thio)urea functionalized Ni(<sc>ii</sc>)-salen complexes
Payong, Jae Elise L.
Leonard, Nadia G.
Anderson-Sanchez, Lauren M.
Ziller, Joseph W.
Yang, Jenny Y.
DALTON TRANSACTIONS, 2024,
[9] Simple and easy functionalization of para-hydroxy POCOP-M (M = Ni(<sc>ii</sc>), Pd(<sc>ii</sc>)) pincer complexes: synthesis of multimetallic species
Serrano-Garcia, Juan S.
Garcia-Eleno, Marco Antonio
Arenaza-Corona, Antonino
Rufino-Felipe, Ernesto
Valdes, Hugo
Hernandez-Ortega, Simon
Morales-Morales, David
DALTON TRANSACTIONS, 2025, 54 (02) : 694 - 699
[10] Cutting-edge green synthesis and characterization of novel Ni(<sc>ii</sc>) and Co(<sc>ii</sc>) fluoroimine complexes: a multifaceted evaluation of anticancer, antioxidant, and antimicrobial activities
Bhatnagar, Shivansh
Jain, Akshita
Sharma, Naveen
Jhankal, Krishna Kumar
Fahmi, Nighat
NEW JOURNAL OF CHEMISTRY, 2025, 49 (10) : 4132 - 4147

← 1 2 3 4 5 →