Reversible CO2 insertion into the silicon-nitrogen σ-bond of an N-heterocyclic iminosilane

被引：1

作者：

Wang, Jingyan ^{[1
]}

Hwang, Gi Byoung ^{[1
]}

Knapp, Caroline E. ^{[1
]}

Wilson, Daniel W. N. ^{[1
]}

机构：

[1] UCL, Dept Chem, 20 Gordon St, London, England

来源：

CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 89期

关键词：

COMPLEXES; CARBON; TRANSFORMATION; CATALYSIS; CAPTURE;

D O I：

10.1039/d4cc04798b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reversible insertion of carbon dioxide into the silicon-nitrogen bond of an N-heterocyclic iminosilane is reported. Solution-phase thermodynamic investigations indicate that this process is thermoneutral and reversible, whereas in the solid-phase CO2 can be stored for extended periods and is only released upon heating to 133 degrees C.

引用

页码：13051 / 13054

页数：4

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