Reversible CO2 insertion into the silicon-nitrogen σ-bond of an N-heterocyclic iminosilane

被引：1

作者：

Wang, Jingyan ^{[1
]}

Hwang, Gi Byoung ^{[1
]}

Knapp, Caroline E. ^{[1
]}

Wilson, Daniel W. N. ^{[1
]}

机构：

[1] UCL, Dept Chem, 20 Gordon St, London, England

来源：

CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 89期

关键词：

COMPLEXES; CARBON; TRANSFORMATION; CATALYSIS; CAPTURE;

D O I：

10.1039/d4cc04798b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reversible insertion of carbon dioxide into the silicon-nitrogen bond of an N-heterocyclic iminosilane is reported. Solution-phase thermodynamic investigations indicate that this process is thermoneutral and reversible, whereas in the solid-phase CO2 can be stored for extended periods and is only released upon heating to 133 degrees C.

引用

页码：13051 / 13054

页数：4

共 50 条

[1] N-Heterocyclic carbene-nitrogen molybdenum catalysts for utilization of CO2
Chen, Fei
Tao, Sheng
Liu, Ning
Dai, Bin
POLYHEDRON, 2021, 196
[2] N-Heterocyclic Carbene Functionalized Polymer for Reversible Fixation-Release of CO2
Zhou, Hui
Zhang, Wen-Zhen
Wang, Yi-Ming
Qu, Jing-Ping
Lu, Xiao-Bing
MACROMOLECULES, 2009, 42 (15) : 5419 - 5421
[3] Reversible CO2 fixation by N-heterocyclic imines forming water-stable zwitterionic nitrogen-base-CO2 adducts
Wilm, Lukas F. B.
Eder, Tobias
Mueck-Lichtenfeld, Christian
Mehlmann, Paul
Wuensche, Marius
Buss, Florenz
Dielmann, Fabian
GREEN CHEMISTRY, 2019, 21 (03) : 640 - 648
[4] Insertion of a N-heterocyclic carbene (NHC) into a platinum-olefin bond
Fantasia, Serena
Jacobsen, Heiko
Cavallo, Luigi
Nolan, Steven P.
ORGANOMETALLICS, 2007, 26 (14) : 3286 - 3288
[5] Photochemical reduction of CO2 using N-heterocyclic carbenes
Denning, Derek
Falvey, Daniel
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 247
[6] The Preparation and Application of N-Heterocyclic Carbene/CO2 Adducts
Wang Yanqin
Li Zhenjiang
Guo Chang
PROGRESS IN CHEMISTRY, 2010, 22 (2-3) : 433 - 439
[7] Comprehensive Basicity Scales for N-Heterocyclic Carbenes in DMSO: Implications on the Stabilities of N-Heterocyclic Carbene and CO2 Adducts
Wang, Zhen
Xue, Xiao-Song
Fu, Yanhua
Ji, Pengju
CHEMISTRY-AN ASIAN JOURNAL, 2020, 15 (01) : 169 - 181
[8] Catalytic hydrogenation of CO2 with unsymmetric N-heterocyclic carbene-nitrogen-phosphine ruthenium complexes
Ji, Li
Cui, Tianhua
Nie, Xufeng
Zheng, Yanling
Zheng, Xueli
Fu, Haiyan
Yuan, Maolin
Chen, Hua
Xu, Jiaqi
Li, Ruixiang
CATALYSIS SCIENCE & TECHNOLOGY, 2021, 11 (21) : 6965 - 6969
[9] A catalytic intramolecular nitrene insertion into a copper(I)-N-heterocyclic carbene bond yielding fused nitrogen heterocycles
Fauche, Kevin
Nauton, Lionel
Jouffret, Laurent
Cisnetti, Federico
Gautier, Arnaud
CHEMICAL COMMUNICATIONS, 2017, 53 (15) : 2402 - 2405
[10] Silicon-Nitrogen Bond Formation via Heterodehydrocoupling and Catalytic N-Silylation
Reuter, Matthew B.
Hageman, Kate
Waterman, Rory
CHEMISTRY-A EUROPEAN JOURNAL, 2021, 27 (10) : 3251 - 3261

← 1 2 3 4 5 →