Recent progress in nonstoichiometric step-growth polymerization

被引：1
|
作者：
Yokawa, Kenta [1 ]
Higashihara, Tomoya [1 ]
机构：
[1] Yamagata Univ, Dept Organ Mat Sci, 4-3-16 Jonan, Yonezawa, Yamagata 9928510, Japan
来源：
POLYMER CHEMISTRY | 2024年 / 16卷 / 01期
关键词：
REACTION-INDUCED CRYSTALLIZATION; NUCLEATION-ELONGATION POLYMERIZATION; SUZUKI-MIYAURA POLYCONDENSATION; COUPLING POLYCONDENSATION; STOICHIOMETRIC IMBALANCE; CYCLIC POLYMERIZATION; AROMATIC POLYESTERS; CONJUGATED POLYMERS; SIZE DISTRIBUTION; OLIGOMERS;
D O I：
10.1039/d4py01091d
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
According to the theory established by Carothers and Flory, stoichiometric control of monomers is necessary for efficient step-growth polymerization of AA-type and BB-type monomers in a single-phase solution. This review examines recent progress in synthesizing high-molecular-weight polymers via atypical nonstoichiometric step-growth polymerization (NSSP). The reactive intermediate mechanism (RIM) and intramolecular catalyst transfer (ICT) systems are essential for efficient NSSP, generating polymers with much higher molecular weights than theoretically predicted. NSSP systems provide many advantages in fine synthetic technologies for producing complex multifunctional polymers suitable for specific applications.
引用
收藏
页码：11 / 26
页数：16
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