Hypervalent iodine chemistry with a mechanochemical twist

被引：1

作者：

Doobary, Sayad ^{[1
]}

Ibanez, Miguel M. de Vries ^{[1
]}

Olofsson, Berit ^{[1
,2
]}

机构：

[1] Stockholm Univ, Dept Organ Chem, Arrhenius Lab, S-106 91 Stockholm, Sweden

[2] Stockholm Univ, Ctr Circular & Sustainable Syst SUCCeSS, S-10691 Stockholm, Sweden

来源：

GREEN CHEMISTRY | 2024年 / 26卷 / 23期

关键词：

METAL-FREE; DIARYLIODONIUM SALTS; ARYLATION;

D O I：

10.1039/d4gc04903a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The combination of mechanochemistry and hypervalent iodine chemistry has rarely been reported, despite the numerous advantages offered by this enabling technology. With this in mind, this study addresses the key issue of transforming hypervalent iodine-mediated, solution-based reactions into the mechanochemical realm, accompanied by benchmarking and sustainability studies of the different types of reactions. Interestingly, several reagents displayed quite different reactivity and regioselectivity under mechanochemical conditions.

引用

页码：11518 / 11523

页数：6

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